Palladium-Catalyzed Transformations of Alkylidenecyclopropanes
Organic synthesis has profoundly impacted fields such as medicinal chemistry, materials science, and agriculture by enabling the creation of complex molecular structures beyond those found in nature. In recent years, the field has embraced sustainable practices aligned with green chemistry principle...
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| Format: | doctoral thesis |
| Publication Date: | 2025 |
| Country: | España |
| Institution: | Universidad de Santiago de Compostela (USC) |
| Repository: | Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela |
| Language: | English |
| OAI Identifier: | oai:minerva.usc.gal:10347/41048 |
| Online Access: | https://hdl.handle.net/10347/41048 |
| Access Level: | Open access |
| Keyword: | alkylidenecyclopropane palladium transition-metal catalysis heterocycles cross-coupling 230610 Compuestos heterocíclicos 230611 Compuestos organometálicos 230615 Mecanismos de reacción |
| Summary: | Organic synthesis has profoundly impacted fields such as medicinal chemistry, materials science, and agriculture by enabling the creation of complex molecular structures beyond those found in nature. In recent years, the field has embraced sustainable practices aligned with green chemistry principles, prioritizing efficiency, environmental responsibility, and atom economy. In this context, catalysis has emerged as a key synthetic tool, driving more selective and efficient reactions, often under milder conditions, and thereby reducing waste and energy consumption. Among homogeneous catalytic methods, where catalysts and reactants are in the same phase, organometallic complexes featuring transition metals stand out for their tunable electronic and steric properties, which have afforded to broaden significantly the range of achievable chemical transformations, making previously challenging reactions feasible. |
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