Gemini histidine based surfactants: Characterization; surface properties and biological activity

New gemini cationic surfactants bearing imidazolium groups as polar heads and alkyl chains of various lengths were prepared using the amino acid histidine as starting material. These surfactants were found to have very low cmc values and reduced the surface tension of water solutions with high effic...

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Detalles Bibliográficos
Autores: Pinazo Gassol, Aurora, Pons Pons, Ramon, Bustelo, Marta, Manresa, Ángeles, Morán, María del Carmen, Raluy, Miriam, Pérez, Lourdes
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2019
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/184031
Acceso en línea:http://hdl.handle.net/10261/184031
Access Level:acceso abierto
Palabra clave:DNA binding
Gemini surfactants
Histidine
Self-assembly
Langmuir monolayers
Antimicrobial activity
Hemolytic activity
Descripción
Sumario:New gemini cationic surfactants bearing imidazolium groups as polar heads and alkyl chains of various lengths were prepared using the amino acid histidine as starting material. These surfactants were found to have very low cmc values and reduced the surface tension of water solutions with high efficiency. Their biological properties, antimicrobial and hemolytic activities, depended on the alkyl chain length. These surfactants are active against a wide range of bacteria including methicillin-resistant Staphylococcus aureus (MRSA). Moreover, these gemini surfactants have good DNA binding capacity. These new gemini surfactants show a great potential in cosmetic, food and pharmaceutical industries.