From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes

Metal-catalyzed reductive coupling reactions between alkenes and alkynes are a long-standing tradition as a way to create complex unsaturated building blocks of value in organic synthesis ventures. Here, we review the general synthetic approaches realized under Co-catalysis utilizing chemical reduct...

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Autores: Tóth, Balázs L., Amos, Stephanie G. E., Kleij, Arjan W.
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/480089
Acceso en línea:http://hdl.handle.net/2072/480089
https://doi.org/10.1039/D4QO02143F
Access Level:acceso abierto
Palabra clave:Química
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spelling From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenesTóth, Balázs L.Amos, Stephanie G. E.Kleij, Arjan W.Química54Metal-catalyzed reductive coupling reactions between alkenes and alkynes are a long-standing tradition as a way to create complex unsaturated building blocks of value in organic synthesis ventures. Here, we review the general synthetic approaches realized under Co-catalysis utilizing chemical reductants, albeit with some limitations in scope and user-friendliness. A more recent advancement shows that these reductive ene–yne coupling reactions can also be accommodated by photoredox catalysis marking a stepping stone in the area, and creating new incentives for this kind of carbon–carbon bond formation and beyond.info:eu-repo/semantics/acceptedVersionRoyal Society of Chemistry2024info:eu-repo/semantics/article18 p.application/pdfhttp://hdl.handle.net/2072/480089https://doi.org/10.1039/D4QO02143FRECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésCERCA Programme/Generalitat de CatalunyaICREAMICINN/MICIU/AEI (PID2020-112684GB-I00, PID2023-149295NB-I00 and Severo Ochoa Excellence Accreditation 2020−2023 CEX2019-000925-S)AGAUR (2017-SGR-232)Attribution 4.0 Internationalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:2072/4800892026-05-29T05:05:01Z
dc.title.none.fl_str_mv From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
title From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
spellingShingle From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
Tóth, Balázs L.
Química
54
title_short From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
title_full From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
title_fullStr From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
title_full_unstemmed From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
title_sort From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
dc.creator.none.fl_str_mv Tóth, Balázs L.
Amos, Stephanie G. E.
Kleij, Arjan W.
author Tóth, Balázs L.
author_facet Tóth, Balázs L.
Amos, Stephanie G. E.
Kleij, Arjan W.
author_role author
author2 Amos, Stephanie G. E.
Kleij, Arjan W.
author2_role author
author
dc.subject.none.fl_str_mv Química
54
topic Química
54
description Metal-catalyzed reductive coupling reactions between alkenes and alkynes are a long-standing tradition as a way to create complex unsaturated building blocks of value in organic synthesis ventures. Here, we review the general synthetic approaches realized under Co-catalysis utilizing chemical reductants, albeit with some limitations in scope and user-friendliness. A more recent advancement shows that these reductive ene–yne coupling reactions can also be accommodated by photoredox catalysis marking a stepping stone in the area, and creating new incentives for this kind of carbon–carbon bond formation and beyond.
publishDate 2024
dc.date.none.fl_str_mv 2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/480089
https://doi.org/10.1039/D4QO02143F
url http://hdl.handle.net/2072/480089
https://doi.org/10.1039/D4QO02143F
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv CERCA Programme/Generalitat de Catalunya
ICREA
MICINN/MICIU/AEI (PID2020-112684GB-I00, PID2023-149295NB-I00 and Severo Ochoa Excellence Accreditation 2020−2023 CEX2019-000925-S)
AGAUR (2017-SGR-232)
dc.rights.none.fl_str_mv Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 18 p.
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,81155

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