Asymmetric hetero Diels-Alder as an access to carbacephams

A short and efficient asymmetric synthesis of the (6R,7S)-7-tert-butoxycarbonylamino-2-ketocarbacepham is described. The key step involves the hetero Diels-Alder reaction of the benzylimine derived from the enantiomer of Garner's aldehyde with Danishefsky's diene.

Bibliographic Details
Authors: Avenoza, A. [0000-0002-5465-3555], Busto, J.H. [0000-0003-4403-4790], Cativiela, C., Corzana, F. [0000-0001-5597-8127], Peregrina, J.M. [0000-0003-3778-7065], Zurbano, M.M. [0000-0001-6370-3537]
Format: article
Status:Published version
Publication Date:2002
Country:España
Institution:Universidad de La Rioja (UR)
Repository:RIUR. Repositorio Institucional de la Universidad de La Rioja
OAI Identifier:oai:portal.dialnet.es:doc/5bbc6905b750603269e8139e
Online Access:https://investigacion.unirioja.es/documentos/5bbc6905b750603269e8139e
Access Level:Open access
id ES_5f856124e51dbcaca3bf9f0a470e1b91
oai_identifier_str oai:portal.dialnet.es:doc/5bbc6905b750603269e8139e
network_acronym_str ES
network_name_str España
repository_id_str
spelling Asymmetric hetero Diels-Alder as an access to carbacephamsAvenoza, A. [0000-0002-5465-3555]Busto, J.H. [0000-0003-4403-4790]Cativiela, C.Corzana, F. [0000-0001-5597-8127]Peregrina, J.M. [0000-0003-3778-7065]Zurbano, M.M. [0000-0001-6370-3537]A short and efficient asymmetric synthesis of the (6R,7S)-7-tert-butoxycarbonylamino-2-ketocarbacepham is described. The key step involves the hetero Diels-Alder reaction of the benzylimine derived from the enantiomer of Garner's aldehyde with Danishefsky's diene.2002info:eu-repo/semantics/articleSubtype: Articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://investigacion.unirioja.es/documentos/5bbc6905b750603269e8139ereponame:RIUR. Repositorio Institucional de la Universidad de La Riojainstname:Universidad de La Rioja (UR)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1021/JO016186Hinfo:eu-repo/semantics/altIdentifier/wos/WOS:000173480500037info:eu-repo/semantics/altIdentifier/pmid/11798338info:eu-repo/semantics/altIdentifier/pissn/0022-3263Asymmetric hetero Diels-Alder as an access to carbacephams, 2002, vol. 67, núm. 2, pág. 598-601info:eu-repo/semantics/openAccessoai:portal.dialnet.es:doc/5bbc6905b750603269e8139e2026-06-14T12:47:17Z
dc.title.none.fl_str_mv Asymmetric hetero Diels-Alder as an access to carbacephams
title Asymmetric hetero Diels-Alder as an access to carbacephams
spellingShingle Asymmetric hetero Diels-Alder as an access to carbacephams
Avenoza, A. [0000-0002-5465-3555]
title_short Asymmetric hetero Diels-Alder as an access to carbacephams
title_full Asymmetric hetero Diels-Alder as an access to carbacephams
title_fullStr Asymmetric hetero Diels-Alder as an access to carbacephams
title_full_unstemmed Asymmetric hetero Diels-Alder as an access to carbacephams
title_sort Asymmetric hetero Diels-Alder as an access to carbacephams
dc.creator.none.fl_str_mv Avenoza, A. [0000-0002-5465-3555]
Busto, J.H. [0000-0003-4403-4790]
Cativiela, C.
Corzana, F. [0000-0001-5597-8127]
Peregrina, J.M. [0000-0003-3778-7065]
Zurbano, M.M. [0000-0001-6370-3537]
author Avenoza, A. [0000-0002-5465-3555]
author_facet Avenoza, A. [0000-0002-5465-3555]
Busto, J.H. [0000-0003-4403-4790]
Cativiela, C.
Corzana, F. [0000-0001-5597-8127]
Peregrina, J.M. [0000-0003-3778-7065]
Zurbano, M.M. [0000-0001-6370-3537]
author_role author
author2 Busto, J.H. [0000-0003-4403-4790]
Cativiela, C.
Corzana, F. [0000-0001-5597-8127]
Peregrina, J.M. [0000-0003-3778-7065]
Zurbano, M.M. [0000-0001-6370-3537]
author2_role author
author
author
author
author
description A short and efficient asymmetric synthesis of the (6R,7S)-7-tert-butoxycarbonylamino-2-ketocarbacepham is described. The key step involves the hetero Diels-Alder reaction of the benzylimine derived from the enantiomer of Garner's aldehyde with Danishefsky's diene.
publishDate 2002
dc.date.none.fl_str_mv 2002
dc.type.none.fl_str_mv info:eu-repo/semantics/article
Subtype: Article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://investigacion.unirioja.es/documentos/5bbc6905b750603269e8139e
url https://investigacion.unirioja.es/documentos/5bbc6905b750603269e8139e
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/JO016186H
info:eu-repo/semantics/altIdentifier/wos/WOS:000173480500037
info:eu-repo/semantics/altIdentifier/pmid/11798338
info:eu-repo/semantics/altIdentifier/pissn/0022-3263
Asymmetric hetero Diels-Alder as an access to carbacephams, 2002, vol. 67, núm. 2, pág. 598-601
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:RIUR. Repositorio Institucional de la Universidad de La Rioja
instname:Universidad de La Rioja (UR)
instname_str Universidad de La Rioja (UR)
reponame_str RIUR. Repositorio Institucional de la Universidad de La Rioja
collection RIUR. Repositorio Institucional de la Universidad de La Rioja
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869409213056286720
score 15,198674

Similar Items