Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations

The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon-nitrogen double bond of the imine to form the 4-membered ring system. The scope of the reaction...

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Detalhes bibliográficos
Autores: Ghashghaei, Ouldouz, Manna, Consiglia Annamaria, Vicente García, Esther, Revés, Marc, Lavilla Grífols, Rodolfo
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2014
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositório:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/120563
Acesso em linha:https://hdl.handle.net/2445/120563
Access Level:Acceso aberto
Palavra-chave:Isonitrils
Imines
Compostos heterocíclics
Reaccions químiques
Química orgànica
Isocyanides
Heterocyclic compounds
Chemical reactions
Organic chemistry
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spelling Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic VariationsGhashghaei, OuldouzManna, Consiglia AnnamariaVicente García, EstherRevés, MarcLavilla Grífols, RodolfoIsonitrilsIminesCompostos heterocíclicsReaccions químiquesQuímica orgànicaIsocyanidesIminesHeterocyclic compoundsChemical reactionsOrganic chemistryThe interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon-nitrogen double bond of the imine to form the 4-membered ring system. The scope of the reaction regarding the imine and isocyanide ranges has been determined, and also some mechanistic variations and structural features have been described.Beilstein Institute2018201820142018info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion6 p.application/pdfhttps://hdl.handle.net/2445/120563Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésReproducció del document publicat a: https://doi.org/10.3762/bjoc.10.3Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 12-17https://doi.org/10.3762/bjoc.10.3cc-by (c) Ghashghaei, Ouldouz et al., 2014http://creativecommons.org/licenses/by/3.0/esinfo:eu-repo/semantics/openAccessoai:recercat.cat:2445/1205632026-05-29T05:05:01Z
dc.title.none.fl_str_mv Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations
title Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations
spellingShingle Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations
Ghashghaei, Ouldouz
Isonitrils
Imines
Compostos heterocíclics
Reaccions químiques
Química orgànica
Isocyanides
Imines
Heterocyclic compounds
Chemical reactions
Organic chemistry
title_short Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations
title_full Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations
title_fullStr Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations
title_full_unstemmed Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations
title_sort Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations
dc.creator.none.fl_str_mv Ghashghaei, Ouldouz
Manna, Consiglia Annamaria
Vicente García, Esther
Revés, Marc
Lavilla Grífols, Rodolfo
author Ghashghaei, Ouldouz
author_facet Ghashghaei, Ouldouz
Manna, Consiglia Annamaria
Vicente García, Esther
Revés, Marc
Lavilla Grífols, Rodolfo
author_role author
author2 Manna, Consiglia Annamaria
Vicente García, Esther
Revés, Marc
Lavilla Grífols, Rodolfo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Isonitrils
Imines
Compostos heterocíclics
Reaccions químiques
Química orgànica
Isocyanides
Imines
Heterocyclic compounds
Chemical reactions
Organic chemistry
topic Isonitrils
Imines
Compostos heterocíclics
Reaccions químiques
Química orgànica
Isocyanides
Imines
Heterocyclic compounds
Chemical reactions
Organic chemistry
description The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon-nitrogen double bond of the imine to form the 4-membered ring system. The scope of the reaction regarding the imine and isocyanide ranges has been determined, and also some mechanistic variations and structural features have been described.
publishDate 2014
dc.date.none.fl_str_mv 2014
2018
2018
2018
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/120563
url https://hdl.handle.net/2445/120563
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.3762/bjoc.10.3
Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 12-17
https://doi.org/10.3762/bjoc.10.3
dc.rights.none.fl_str_mv cc-by (c) Ghashghaei, Ouldouz et al., 2014
http://creativecommons.org/licenses/by/3.0/es
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by (c) Ghashghaei, Ouldouz et al., 2014
http://creativecommons.org/licenses/by/3.0/es
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 6 p.
application/pdf
dc.publisher.none.fl_str_mv Beilstein Institute
publisher.none.fl_str_mv Beilstein Institute
dc.source.none.fl_str_mv Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,81155

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