Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations
The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon-nitrogen double bond of the imine to form the 4-membered ring system. The scope of the reaction...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2014 |
| País: | España |
| Institución: | Universidad de Barcelona |
| Repositorio: | Dipòsit Digital de la UB |
| OAI Identifier: | oai:diposit.ub.edu:2445/120563 |
| Acceso en línea: | https://hdl.handle.net/2445/120563 |
| Access Level: | acceso abierto |
| Palabra clave: | Isonitrils Imines Compostos heterocíclics Reaccions químiques Química orgànica Isocyanides Heterocyclic compounds Chemical reactions Organic chemistry |
| Sumario: | The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon-nitrogen double bond of the imine to form the 4-membered ring system. The scope of the reaction regarding the imine and isocyanide ranges has been determined, and also some mechanistic variations and structural features have been described. |
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