Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations
The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon-nitrogen double bond of the imine to form the 4-membered ring system. The scope of the reaction...
| Authors: | , , , , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2014 |
| Country: | España |
| Institution: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repository: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2445/120563 |
| Online Access: | https://hdl.handle.net/2445/120563 |
| Access Level: | Open access |
| Keyword: | Isonitrils Imines Compostos heterocíclics Reaccions químiques Química orgànica Isocyanides Heterocyclic compounds Chemical reactions Organic chemistry |
| Summary: | The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon-nitrogen double bond of the imine to form the 4-membered ring system. The scope of the reaction regarding the imine and isocyanide ranges has been determined, and also some mechanistic variations and structural features have been described. |
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