Valorization of native grape pomace through vesicular nanocarriers for the enhanced delivery of high-value natural bioactive compounds in green cosmeceutical applications

Agro-industrial by-products such as grape pomace represent a sustainable source of bioactive phenolic compounds; however, their practical application in cosmeceutical formulations is limited by their chemical instability, heterogeneous composition, and low skin bioavailability. Although vesicular na...

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Detalhes bibliográficos
Autores: Leyva Jimenez , Francisco Javier, Rodrigo Gallego, Silvia, Castangia , Ines, Rodrigues , Francisca, Manca , Maria Letizia, Alañón Pardo, María Elena
Formato: artículo
Fecha de publicación:2026
País:España
Recursos:Universidad de Castilla-La Mancha
Repositorio:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:dnet:ruidera_____::b89a58e1a98154fb503e526d6f1323a9
Acesso em linha:https://doi.org/10.1016/j.scp.2026.102435
https://www.sciencedirect.com/science/article/pii/S2352554126001270
https://hdl.handle.net/10578/48542
Access Level:acceso abierto
Palavra-chave:Cosmeceutical application
Grape pomace
Phospholipid vesicles
Upcycling
Descrição
Resumo:Agro-industrial by-products such as grape pomace represent a sustainable source of bioactive phenolic compounds; however, their practical application in cosmeceutical formulations is limited by their chemical instability, heterogeneous composition, and low skin bioavailability. Although vesicular nanocarriers have been widely proposed to overcome these limitations, their interaction with complex polyphenolic matrices remains poorly understood, and comparative studies across different vesicle types are still scarce. In this context, the present work tests the hypothesis that the composition and physicochemical properties of vesicular systems differentially modulate the encapsulation efficiency, stability, and biological activity of grape pomace-derived phenolics. Grape pomace extracts from three red grape varieties (Cabernet Sauvignon, Malbec, Tinto de la P´ ampana Blanca) were obtained using a green extraction approach and characterized in terms of yield, total phenolic content and antioxidant capacity. The most promising extract, Tinto de la P´ ampana Blanca, was incorporated into four vesicular systems (liposomes, ethosomes, trans fersomes and Transcutol® P penetration enhancer containing vesicles (PEVs)) which were eval uated in terms of physicochemical properties, encapsulation efficiency and biological performance in keratinocytes under oxidative stress. Results demonstrate that vesicle composition significantly influences both colloidal stability and biological response.