Synthesis and structure of [Tl(C6F5)2Cl{Au(C6F5)3(PPh2CH2PPh2(O))}2].

Two trinuclear gold-thallium-gold complexes, [T1(C6F5)2X{Au(C6F5)3(PPH2CH2PPh2CH2PPh2(O))}2} (X = C6F5, C1), have been synthesised by reaction of [Au(C6F5)3(PPh2(O))] with [T1(C6F5)2C1] or [T1(C6F5)3(diox)], in which the phosphine oxide moiety coordinates to thallium; the crystal structure of the fo...

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Detalles Bibliográficos
Autores: Alvarez, B., Fernández, E.J. [0000-0002-6501-744X], Gimeno, M.C. [0000-0003-0553-0695], Jones, P.G., Laguna, A. [0000-0003-1984-7538], Laguna, M. [0000-0002-5801-3352], López-de-Luzuriaga, J.M. [0000-0001-5767-8734]
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:1996
País:España
Institución:Universidad de La Rioja (UR)
Repositorio:RIUR. Repositorio Institucional de la Universidad de La Rioja
OAI Identifier:oai:portal.dialnet.es:doc/5bbc683cb750603269e80520
Acceso en línea:https://investigacion.unirioja.es/documentos/5bbc683cb750603269e80520
Access Level:acceso abierto
Palabra clave:Crystal structure
Gold
Pentaflorophenyl
Thallium
Descripción
Sumario:Two trinuclear gold-thallium-gold complexes, [T1(C6F5)2X{Au(C6F5)3(PPH2CH2PPh2CH2PPh2(O))}2} (X = C6F5, C1), have been synthesised by reaction of [Au(C6F5)3(PPh2(O))] with [T1(C6F5)2C1] or [T1(C6F5)3(diox)], in which the phosphine oxide moiety coordinates to thallium; the crystal structure of the former product has been established by X-ray diffraction.

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