[Au(C6F5)3(PPh2H)]: A Precursor for the Synthesis of Gold(III) Phosphide Complexes
The covalent radius of Au(I) is about 0.07 Å smaller than that of Ag(I). This was determined from the crystal structures of the isostructural complexes [N(PPh3][{Au(C6F5)3-(μ-PPh2)}2M] (M = Au (structure shown in the picture), Ag). These mixed Au(III)-M phosphides were synthesized from [Au(C6F5)3-(P...
| Autores: | , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 1998 |
| País: | España |
| Institución: | Universidad de La Rioja (UR) |
| Repositorio: | RIUR. Repositorio Institucional de la Universidad de La Rioja |
| OAI Identifier: | oai:portal.dialnet.es:doc/5bbc683eb750603269e8053c |
| Acceso en línea: | https://investigacion.unirioja.es/documentos/5bbc683eb750603269e8053c |
| Access Level: | acceso abierto |
| Palabra clave: | Copper Gold P ligands Silver |
| Sumario: | The covalent radius of Au(I) is about 0.07 Å smaller than that of Ag(I). This was determined from the crystal structures of the isostructural complexes [N(PPh3][{Au(C6F5)3-(μ-PPh2)}2M] (M = Au (structure shown in the picture), Ag). These mixed Au(III)-M phosphides were synthesized from [Au(C6F5)3-(PPh2H)], the first gold complex to contain a secondary phosphane. |
|---|