Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis
The activation of molecules through intramolecular hydrogen-bond formation to promote chemical reactions appears as a suitable strategy in organic synthesis, especially for the preparation of chiral compounds under metal and organocatalytic conditions. The use of this interaction has enabled reactiv...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Universidad Autónoma de Madrid |
| Repositorio: | Biblos-e Archivo. Repositorio Institucional de la UAM |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.uam.es:10486/702717 |
| Acceso en línea: | http://hdl.handle.net/10486/702717 https://dx.doi.org/10.1021/acsorginorgau.1c00053 |
| Access Level: | acceso abierto |
| Palabra clave: | Intramolecular activation, Hydrogen bonding Organocatalysis Metal catalysis Bifunctional catalysis Asymmetric synthesis Química |
| Sumario: | The activation of molecules through intramolecular hydrogen-bond formation to promote chemical reactions appears as a suitable strategy in organic synthesis, especially for the preparation of chiral compounds under metal and organocatalytic conditions. The use of this interaction has enabled reactivity enhancement of reagents, as well as stabilization of the chemical species and enantiocontrol of the processes |
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