Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O

The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-​C5Me5)​3(μ-​O)​4}​2(μ-​O)​]​, exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centers present the typical three-​legged piano-​stool coordination environment, where one site is occupied by a pentame...

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Detalhes bibliográficos
Autores: Pérez Redondo, Adrián|||0000-0002-0086-8825, Martín Alonso, Avelino|||0000-0002-9776-9670
Formato: artículo
Fecha de publicación:2015
País:España
Recursos:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/35840
Acesso em linha:http://hdl.handle.net/10017/35840
https://dx.doi.org/10.1107/S2056989015004041
Access Level:acceso abierto
Palavra-chave:crystal structure
titanium oxide
penta­methyl­cyclo­penta­dienyl ligand
organometallic
Química
Chemistry
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repository_id_str
spelling Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O1:3κ2O:O2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}Pérez Redondo, Adrián|||0000-0002-0086-8825Martín Alonso, Avelino|||0000-0002-9776-9670crystal structuretitanium oxidepenta­methyl­cyclo­penta­dienyl ligandorganometallicQuímicaChemistryThe title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-​C5Me5)​3(μ-​O)​4}​2(μ-​O)​]​, exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centers present the typical three-​legged piano-​stool coordination environment, where one site is occupied by a pentamethylcyclopentadienyl ligand linked in an η5-​coordination fashion, while three bridging O atoms fill the other three sites.Comisión Asesora de Investigación Científica y Técnica20152015-03-21journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/35840https://dx.doi.org/10.1107/S2056989015004041reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengCAICYT Plan Nacional de I+D+i 2008-2011 CSD2006-00015 FACTORÍA DE CRISTALIZACIÓNopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-ShareAlike 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/358402026-06-18T11:13:07Z
dc.title.none.fl_str_mv Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O
1:3κ2O:O
2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
title Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O
spellingShingle Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O
Pérez Redondo, Adrián|||0000-0002-0086-8825
crystal structure
titanium oxide
penta­methyl­cyclo­penta­dienyl ligand
organometallic
Química
Chemistry
title_short Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O
title_full Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O
title_fullStr Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O
title_full_unstemmed Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O
title_sort Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O
dc.creator.none.fl_str_mv Pérez Redondo, Adrián|||0000-0002-0086-8825
Martín Alonso, Avelino|||0000-0002-9776-9670
author Pérez Redondo, Adrián|||0000-0002-0086-8825
author_facet Pérez Redondo, Adrián|||0000-0002-0086-8825
Martín Alonso, Avelino|||0000-0002-9776-9670
author_role author
author2 Martín Alonso, Avelino|||0000-0002-9776-9670
author2_role author
dc.subject.none.fl_str_mv crystal structure
titanium oxide
penta­methyl­cyclo­penta­dienyl ligand
organometallic
Química
Chemistry
topic crystal structure
titanium oxide
penta­methyl­cyclo­penta­dienyl ligand
organometallic
Química
Chemistry
description The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-​C5Me5)​3(μ-​O)​4}​2(μ-​O)​]​, exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centers present the typical three-​legged piano-​stool coordination environment, where one site is occupied by a pentamethylcyclopentadienyl ligand linked in an η5-​coordination fashion, while three bridging O atoms fill the other three sites.
publishDate 2015
dc.date.none.fl_str_mv 2015
2015-03-21
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/35840
https://dx.doi.org/10.1107/S2056989015004041
url http://hdl.handle.net/10017/35840
https://dx.doi.org/10.1107/S2056989015004041
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv CAICYT Plan Nacional de I+D+i 2008-2011 CSD2006-00015 FACTORÍA DE CRISTALIZACIÓN
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-ShareAlike 4.0 International
http://creativecommons.org/licenses/by-nc-sa/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-ShareAlike 4.0 International
http://creativecommons.org/licenses/by-nc-sa/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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