Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV)
The molecule of the title organometallic hafnium(IV) compound, [Hf(CH3) 3(C 13H 21)] or [HfMe3( η 5-C 5H 3-1,3- tBu 2)], adopts the classical three-legged piano-stool geometry for monocyclopentadienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The...
| Autores: | , , |
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| Tipo de recurso: | conjunto de datos |
| Estado: | Versión publicada |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Consorcio Madroño |
| Repositorio: | e-cienciaDatos, Repositorio de Datos del Consorcio Madroño |
| OAI Identifier: | doi:10.21950/BCYB9Y |
| Acceso en línea: | https://doi.org/10.21950/BCYB9Y |
| Access Level: | acceso abierto |
| Palabra clave: | Chemistry Crystal structure Hafnium Cyclopentadienyl ligand Organometallic compound. |
| Sumario: | The molecule of the title organometallic hafnium(IV) compound, [Hf(CH3) 3(C 13H 21)] or [HfMe3( η 5-C 5H 3-1,3- tBu 2)], adopts the classical three-legged piano-stool geometry for monocyclopentadienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The C atoms of the two tert-butyl group bonded to the cyclopentadienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-squares plane. There are no significant intermolecular interactions present between the molecules in the crystal structure. |
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