Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O
The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centers present the typical three-legged piano-stool coordination environment, where one site is occupied by a pentame...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/35840 |
| Acceso en línea: | http://hdl.handle.net/10017/35840 https://dx.doi.org/10.1107/S2056989015004041 |
| Access Level: | acceso abierto |
| Palabra clave: | crystal structure titanium oxide pentamethylcyclopentadienyl ligand organometallic Química Chemistry |
| Sumario: | The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centers present the typical three-legged piano-stool coordination environment, where one site is occupied by a pentamethylcyclopentadienyl ligand linked in an η5-coordination fashion, while three bridging O atoms fill the other three sites. |
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