(?, T, p) Measurements of the Methyl Nonafluorobutyl Ether (HFE-7100) + 1-Propanol Mixture at Pressures up to 70 MPa and Temperatures from 298.15 to 393.15 K

The characterization of the thermophysical properties of new environmentally friendly fluids, such as hydrofluoroether fluids (HFEs) and their mixtures with other compounds, is necessary nowadays in order to properly design the machinery and piping networks involved in their utilization. However, sc...

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Autores: Muñoz Rujas, Natalia, Rubio Pérez, Gabriel, García Alonso, Jesús M., Briones Llorente, Raúl, Ezzahra Yatim, Fátima, Aguilar, Fernando
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Consejo General de la Arquitectura Técnica de España (CGATE)
Repositorio:RIARTE
OAI Identifier:oai:www.riarte.es:20.500.12251/3786
Acceso en línea:http://hdl.handle.net/20.500.12251/3786
https://doi.org/10.1021/acs.jced.3c00563
Access Level:acceso abierto
Palabra clave:Fluidos de hidrofluoroéter (HFE)
Ensayos (propiedades o materiales)
Propiedades químicas
2204.03 Flujo de Fluidos
2205.04 Mecánica de Fluidos
3312.08 Propiedades de Los Materiales
3312.12 Ensayo de Materiales
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spelling (?, T, p) Measurements of the Methyl Nonafluorobutyl Ether (HFE-7100) + 1-Propanol Mixture at Pressures up to 70 MPa and Temperatures from 298.15 to 393.15 KMuñoz Rujas, NataliaRubio Pérez, GabrielGarcía Alonso, Jesús M.Briones Llorente, RaúlEzzahra Yatim, FátimaAguilar, FernandoFluidos de hidrofluoroéter (HFE)Ensayos (propiedades o materiales)Propiedades químicas2204.03 Flujo de Fluidos2205.04 Mecánica de Fluidos3312.08 Propiedades de Los Materiales3312.12 Ensayo de MaterialesThe characterization of the thermophysical properties of new environmentally friendly fluids, such as hydrofluoroether fluids (HFEs) and their mixtures with other compounds, is necessary nowadays in order to properly design the machinery and piping networks involved in their utilization. However, scarce data concerning these kinds of fluids are actually available. In this work, new experimental high pressure density data (742 points) for the binary system x HFE-7100 + (1 – x) 1-propanol are presented. This property was measured by using an Anton Paar vibrating tube densitometer in the temperature range of 298.15–393.15 K and in the pressure interval of 0.1–70 MPa. A comparison between our experimental high pressure density data and those found in the literature was carried out only for the pure compounds, since no density data for the binary mixture were found. To perform this comparison, we used a Tait-like equation in order to correlate our results to those of the literature. Concerning the experimental density data, the derivative properties of isothermal compressibility, κT, and isobaric expansion, αP, were determined over the same pressure and temperature ranges. Excess molar volumes of the binary system were also determined and compared with those of the mixture x HFE-7100 + (1 – x) 2-propanol published in one of our previous works.AMER CHEMICAL SOC2024info:eu-repo/semantics/articlehttp://hdl.handle.net/20.500.12251/3786https://doi.org/10.1021/acs.jced.3c00563reponame:RIARTEinstname:Consejo General de la Arquitectura Técnica de España (CGATE)Ingléshttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:www.riarte.es:20.500.12251/37862026-06-02T12:44:41Z
dc.title.none.fl_str_mv (?, T, p) Measurements of the Methyl Nonafluorobutyl Ether (HFE-7100) + 1-Propanol Mixture at Pressures up to 70 MPa and Temperatures from 298.15 to 393.15 K
title (?, T, p) Measurements of the Methyl Nonafluorobutyl Ether (HFE-7100) + 1-Propanol Mixture at Pressures up to 70 MPa and Temperatures from 298.15 to 393.15 K
spellingShingle (?, T, p) Measurements of the Methyl Nonafluorobutyl Ether (HFE-7100) + 1-Propanol Mixture at Pressures up to 70 MPa and Temperatures from 298.15 to 393.15 K
Muñoz Rujas, Natalia
Fluidos de hidrofluoroéter (HFE)
Ensayos (propiedades o materiales)
Propiedades químicas
2204.03 Flujo de Fluidos
2205.04 Mecánica de Fluidos
3312.08 Propiedades de Los Materiales
3312.12 Ensayo de Materiales
title_short (?, T, p) Measurements of the Methyl Nonafluorobutyl Ether (HFE-7100) + 1-Propanol Mixture at Pressures up to 70 MPa and Temperatures from 298.15 to 393.15 K
title_full (?, T, p) Measurements of the Methyl Nonafluorobutyl Ether (HFE-7100) + 1-Propanol Mixture at Pressures up to 70 MPa and Temperatures from 298.15 to 393.15 K
title_fullStr (?, T, p) Measurements of the Methyl Nonafluorobutyl Ether (HFE-7100) + 1-Propanol Mixture at Pressures up to 70 MPa and Temperatures from 298.15 to 393.15 K
title_full_unstemmed (?, T, p) Measurements of the Methyl Nonafluorobutyl Ether (HFE-7100) + 1-Propanol Mixture at Pressures up to 70 MPa and Temperatures from 298.15 to 393.15 K
title_sort (?, T, p) Measurements of the Methyl Nonafluorobutyl Ether (HFE-7100) + 1-Propanol Mixture at Pressures up to 70 MPa and Temperatures from 298.15 to 393.15 K
dc.creator.none.fl_str_mv Muñoz Rujas, Natalia
Rubio Pérez, Gabriel
García Alonso, Jesús M.
Briones Llorente, Raúl
Ezzahra Yatim, Fátima
Aguilar, Fernando
author Muñoz Rujas, Natalia
author_facet Muñoz Rujas, Natalia
Rubio Pérez, Gabriel
García Alonso, Jesús M.
Briones Llorente, Raúl
Ezzahra Yatim, Fátima
Aguilar, Fernando
author_role author
author2 Rubio Pérez, Gabriel
García Alonso, Jesús M.
Briones Llorente, Raúl
Ezzahra Yatim, Fátima
Aguilar, Fernando
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Fluidos de hidrofluoroéter (HFE)
Ensayos (propiedades o materiales)
Propiedades químicas
2204.03 Flujo de Fluidos
2205.04 Mecánica de Fluidos
3312.08 Propiedades de Los Materiales
3312.12 Ensayo de Materiales
topic Fluidos de hidrofluoroéter (HFE)
Ensayos (propiedades o materiales)
Propiedades químicas
2204.03 Flujo de Fluidos
2205.04 Mecánica de Fluidos
3312.08 Propiedades de Los Materiales
3312.12 Ensayo de Materiales
description The characterization of the thermophysical properties of new environmentally friendly fluids, such as hydrofluoroether fluids (HFEs) and their mixtures with other compounds, is necessary nowadays in order to properly design the machinery and piping networks involved in their utilization. However, scarce data concerning these kinds of fluids are actually available. In this work, new experimental high pressure density data (742 points) for the binary system x HFE-7100 + (1 – x) 1-propanol are presented. This property was measured by using an Anton Paar vibrating tube densitometer in the temperature range of 298.15–393.15 K and in the pressure interval of 0.1–70 MPa. A comparison between our experimental high pressure density data and those found in the literature was carried out only for the pure compounds, since no density data for the binary mixture were found. To perform this comparison, we used a Tait-like equation in order to correlate our results to those of the literature. Concerning the experimental density data, the derivative properties of isothermal compressibility, κT, and isobaric expansion, αP, were determined over the same pressure and temperature ranges. Excess molar volumes of the binary system were also determined and compared with those of the mixture x HFE-7100 + (1 – x) 2-propanol published in one of our previous works.
publishDate 2024
dc.date.none.fl_str_mv 2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12251/3786
https://doi.org/10.1021/acs.jced.3c00563
url http://hdl.handle.net/20.500.12251/3786
https://doi.org/10.1021/acs.jced.3c00563
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv AMER CHEMICAL SOC
publisher.none.fl_str_mv AMER CHEMICAL SOC
dc.source.none.fl_str_mv reponame:RIARTE
instname:Consejo General de la Arquitectura Técnica de España (CGATE)
instname_str Consejo General de la Arquitectura Técnica de España (CGATE)
reponame_str RIARTE
collection RIARTE
repository.name.fl_str_mv
repository.mail.fl_str_mv
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