Cerium-doped SrHfO3 sol-gel films
SrHfO3 presents high density, which makes it interesting for host lattice when it is doped with rare earths for luminescent materials. The optical and structural studies of Ce3+-doped strontium hafnate films prepared by the sol-gel process are presented in this work. Crack-free films with waveguidin...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2010 |
| País: | Brasil |
| Institución: | Matéria (Rio de Janeiro. Online) |
| Repositorio: | Matéria (Rio de Janeiro. Online) |
| Idioma: | inglés |
| OAI Identifier: | oai:scielo:S1517-70762010000400005 |
| Acceso en línea: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762010000400005 |
| Access Level: | acceso abierto |
| Palabra clave: | SrHfO3 sol-gel thin films planar waveguide scintillating film |
| Sumario: | SrHfO3 presents high density, which makes it interesting for host lattice when it is doped with rare earths for luminescent materials. The optical and structural studies of Ce3+-doped strontium hafnate films prepared by the sol-gel process are presented in this work. Crack-free films with waveguiding performances were obtained with heat-treatments between 400°C and 700°C. The total elimination of organic compounds occurs above 800°C as indicated by Fourier transform infrared spectroscopy. The optogeometric properties (refractive index and thickness) are investigated by m-lines spectroscopy. Films structure is analysed using X-ray diffraction and transmission electron microscopy. The films crystallise from amorphous phase to pure SrHfO3 orthorhombic phase at 750°C. The HfO2 monoclinic phase superposes to SrHfO3 orthorhombic phase after heat treatment performed at 1000°C. Finally, the potentiality to prepare Ce3+ activated SrHfO3 sol-gel films with scintillation properties is explored. |
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