Phonon optical modes and electronic properties in diamond nanowires

A local bond-polarization model based on the displacement–displacement Green’s function and the Born potential are applied to study the confined optical phonons and Raman scattering of diamond nanowires (DNWs). Also, the electronic band structure of DNWs are investigated by means of a semi-empirical...

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Detalles Bibliográficos
Autores: José Alejandro Díaz Méndez, MIGUEL CRUZ IRISSON
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2011
País:México
Institución:Instituto Nacional de Astrofísica, Óptica y Electrónica
Repositorio:Repositorio Institucional del INAOE
Idioma:inglés
OAI Identifier:oai:inaoe.repositorioinstitucional.mx:1009/1725
Acceso en línea:http://inaoe.repositorioinstitucional.mx/jspui/handle/1009/1725
Access Level:acceso abierto
Palabra clave:info:eu-repo/classification/Diamond/Diamond
info:eu-repo/classification/Nanowires/Nanowires
info:eu-repo/classification/Tight-binding/Tight-binding
info:eu-repo/classification/Phonons/Phonons
info:eu-repo/classification/Raman scattering/Raman scattering
info:eu-repo/classification/cti/1
info:eu-repo/classification/cti/22
info:eu-repo/classification/cti/2203
Descripción
Sumario:A local bond-polarization model based on the displacement–displacement Green’s function and the Born potential are applied to study the confined optical phonons and Raman scattering of diamond nanowires (DNWs). Also, the electronic band structure of DNWs are investigated by means of a semi-empirical tightbinding approach and compared with density functional theory within local density approximation. The supercell technique is applied to model DNWs along [0 0 1] direction preserving the crystalline diamond atomic structure. The results of both phonons and electrons show a clear quantum confinement signature. Moreover, the highest energy Raman peak shows a shift towards low frequencies respect to the bulk crystalline diamond, in agreement with experimental data.