Theory of 45 degrees reflectometry from metal surfaces

The use of optical spectroscopies to study surfaces is hindered by the difficulty of disentangling bulk and surface contributions to the signal. According to Fresnel formulae, the a and p reflectances R of a semi-infinite system obey the simple relation Delta = R-s(2) - R-p = 0 when the incidence an...

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Detalles Bibliográficos
Autores: Maytorena, JA, Mochan, WL, López-Bastidas, C
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:1998
País:México
Institución:Universidad Nacional Autónoma de México
Repositorio:Sistema de Información de la Facultad de Ciencias, UNAM
OAI Identifier:oai:repositorio.fciencias.unam.mx:11154/2693
Acceso en línea:http://hdl.handle.net/11154/2693
Access Level:acceso abierto
Palabra clave:Materials Science, Multidisciplinary
Physics, Applied
Physics, Condensed Matter
Descripción
Sumario:The use of optical spectroscopies to study surfaces is hindered by the difficulty of disentangling bulk and surface contributions to the signal. According to Fresnel formulae, the a and p reflectances R of a semi-infinite system obey the simple relation Delta = R-s(2) - R-p = 0 when the incidence angle is 45 degrees. Deviations from this result can be related to microscopic surface contributions to R. In this paper we study theoretically Delta for metal surfaces. For a semi-infinite nat jellium we obtain the contributions to Delta from electronic excitations at the surface. To explore Delta for non-jellium conductors, we apply a 'Swiss cheese' model to different surfaces of Ag.