Synthesis and characterization of (R)-(+)-alpha-methylbenzylmethacryloylamine. A novel and versatile monomer

We synthesized (R)-(+)-alpha-methylbenzylmethacryloylamine from the condensation reaction of methacryloyl chloride with (R)-(+)-alpha-methylbenzylamine in order to make a prototype molecule that can mimic some of the necessary characteristics of nonlinear optical (NLO) materials and that could also...

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Detalles Bibliográficos
Autores: Gutierrez-Perez, R, Percino, MJ, Chapela, VM, Alvarez, C
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:1999
País:México
Institución:Universidad Nacional Autónoma de México
Repositorio:Sistema de Información de la Facultad de Ciencias, UNAM
OAI Identifier:oai:repositorio.fciencias.unam.mx:11154/2123
Acceso en línea:http://hdl.handle.net/11154/2123
Access Level:acceso abierto
Palabra clave:Polymer Science
(R)-(+)-alpha-methylbenzylmethacryloylamine
chiral monomer
NLO properties
Descripción
Sumario:We synthesized (R)-(+)-alpha-methylbenzylmethacryloylamine from the condensation reaction of methacryloyl chloride with (R)-(+)-alpha-methylbenzylamine in order to make a prototype molecule that can mimic some of the necessary characteristics of nonlinear optical (NLO) materials and that could also display potential chiral polymer catalyst properties. The structure of the new monomer (R)-(+)-alpha-methylbenzylmethacryloylamine along with the formation of the corresponding polymer was determined by NMR and IR spectroscopy.