Synthesis of intercalated Al-hydroxy-montmorillonite

Montmorillonite from Durango, Mexico, of composition(Si3.88Al0.12)(Al1.41Mg0.59)O10(OH)2(Ca0.07Mg0.11Na0.28K0.06), surface area42.07 m2g-1, d001 spacing 12.50 Å, and pore volume 0.002 cm3g-1, wasintercalated with Al-hydroxy oligomer. The modified clay developeda surface area of 287.86 m2g-1, pore vo...

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Detalles Bibliográficos
Autores: Liberto de Pablo-Galán, M. Pilar Saucedo-Ramírez, M. de Lourdes Chávez-García
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2006
País:México
Institución:Universidad Nacional Autónoma de México
Repositorio:Redalyc-UNAM
OAI Identifier:oai:redalyc.org:47550107
Acceso en línea:https://www.redalyc.org/articulo.oa?id=47550107
Access Level:acceso abierto
Palabra clave:Química
clays
oligomer
silicates
Intercalated aluminum montmorillonite
Descripción
Sumario:Montmorillonite from Durango, Mexico, of composition(Si3.88Al0.12)(Al1.41Mg0.59)O10(OH)2(Ca0.07Mg0.11Na0.28K0.06), surface area42.07 m2g-1, d001 spacing 12.50 Å, and pore volume 0.002 cm3g-1, wasintercalated with Al-hydroxy oligomer. The modified clay developeda surface area of 287.86 m2g-1, pore volume of 0.103 cm3g-1, and d001spacing of 18.70 Å. Dehydration to 70 °C shift the d001 spacing to17.29 Å; dehydroxylation started at 150 °C and by 300 °C had lost1.92 w% and reduced the d001 spacing to 17.34 Å.