Study of lanthanum local structure in montmorillonite

The local structure of the interlamellar lanthanide ions in montmorillonite upon heating is studied. The analysis of the EXAFS data has been carried out using two model environments, that of La3+ aquocomplex and that of the lanthanum oxide. The information thus obtained is crucial in elucidating the...

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Detalles Bibliográficos
Autores: Muñoz Páez, Adela, Alba Carranza, María Dolores, Alvero Reina, Rafael, Castro Arroyo, Miguel Ángel, Trillo de Leyva, José María
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:1993
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/97054
Acceso en línea:https://hdl.handle.net/11441/97054
https://doi.org/10.7567/JJAPS.32S2.779
Access Level:acceso abierto
Palabra clave:EXAFS
Intercalation mechanism
Montmorillonite
Rare earth
Descripción
Sumario:The local structure of the interlamellar lanthanide ions in montmorillonite upon heating is studied. The analysis of the EXAFS data has been carried out using two model environments, that of La3+ aquocomplex and that of the lanthanum oxide. The information thus obtained is crucial in elucidating the intercalation mechanism and demonstrates the important role that XAFS techniques can play in the knowledge of the location and environment of the exchangeable ions in layered silicates.