Kinetic, thermodynamic, physicochemical, and economical characterization of pectin from Mangifera indica L. cv. Haden residues

The effect of temperature (60, 70, 80, and 90 °C) and time (30, 45, 60, 75, and 90 min) on citric acid extraction of Haden mango (Mangifera indica L. cv. Haden) peel pectin was evaluated in the present study. In order to obtain a better understanding of both the extraction process and the characteri...

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Detalhes bibliográficos
Autores: Sergio Valdivia-Rivera, IVAN EMANUEL HERRERA POOL, Teresa del Rosario Ayora_Talavera, MANUEL ALEJANDRO LIZARDI JIMENEZ, NORBERTO ULISES GARCIA CRUZ, Juan C. Cuevas-Bernardino, JOSE MANUEL CERVANTES UC, Neith Pacheco López
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:México
Recursos:Centro de Investigación Científica de Yucatán
Repositorio:Repositorio Institucional CICY
Idioma:inglés
OAI Identifier:oai:cicy.repositorioinstitucional.mx:1003/2106
Acesso em linha:http://cicy.repositorioinstitucional.mx/jspui/handle/1003/2106
Access Level:acceso abierto
Palavra-chave:info:eu-repo/classification/Autores/HADEN MANGO (MANGIFERA INDICA L.)
info:eu-repo/classification/Autores/PECTIN
info:eu-repo/classification/Autores/THERMODYNAMIC
info:eu-repo/classification/Autores/EXTRACTION KINETIC
info:eu-repo/classification/Autores/PHYSICOCHEMICAL CHARACTERIZATION
info:eu-repo/classification/Autores/CITRIC ACID EXTRACTION
info:eu-repo/classification/cti/2
info:eu-repo/classification/cti/24
info:eu-repo/classification/cti/2415
info:eu-repo/classification/cti/241502
Descrição
Resumo:The effect of temperature (60, 70, 80, and 90 °C) and time (30, 45, 60, 75, and 90 min) on citric acid extraction of Haden mango (Mangifera indica L. cv. Haden) peel pectin was evaluated in the present study. In order to obtain a better understanding of both the extraction process and the characteristics of the pectin (obtained from an agro-industrial waste) for a future scaling process, the following characterizations were performed: (1) Kinetic, with the maximum extraction times and yields at all evaluated temperatures; (2) thermodynamic, obtaining activation energies, enthalpies, entropies, and Gibbs free energies for each stage of the process; (3) physicochemical (chemical analysis, monosaccharide composition, degree of esterification, galacturonic acid content, free acidity, Fourier-transform infrared spectroscopy, thermogravimetric and derivative thermogravimetric analyses); and (4) economical, of the pectin with the highest yield. The Haden mango peel pectin was found to be characterized by a high-esterified degree (81.81 ± 0.00%), regular galacturonic acid content (71.57 ± 1.26%), low protein (0.83 ± 0.05%) and high ash (3.53 ± 0.02%) content, low mean viscometric molecular weight (55.91 kDa), and high equivalent weight (3657.55 ± 8.41), which makes it potentially useful for food applications.