Persistent organic pollutants in sediment cores from the southern region of the Bight of the Californias

 In January 1998, four sediment cores were collected to reconstruct the history of contamination by persistent organic compounds in the southern region of the Bight of the Californias. Two groups of compounds were determined using chromatographic methods: petroleum hydrocarbons (aliphatic h...

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Detalles Bibliográficos
Autores: Partida-Gutiérrez, DI, Villaescusa, JA, Macías-Zamora, JV, Castillón, FF
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2003
País:México
Institución:UNIVERSIDAD AUTÓNOMA DE BAJA CALIFORNIA
Repositorio:Ciencias Marinas
Idioma:inglés
OAI Identifier:oai:cienciasmarinas.com.mx:article/164
Acceso en línea:https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/164
Access Level:acceso abierto
Palabra clave:persistent organic compounds
sediment cores
Bight of the Californias
compuestos orgánicos persistentes
núcleos de sedimentos
Cuenca de las Californias
Descripción
Sumario: In January 1998, four sediment cores were collected to reconstruct the history of contamination by persistent organic compounds in the southern region of the Bight of the Californias. Two groups of compounds were determined using chromatographic methods: petroleum hydrocarbons (aliphatic hydrocarbons, AHs, and polynuclear aromatic hydrocarbons, PAHs) and chlorinated hydrocarbons (pesticides and polychlorinated biphenyls, PCBs). The AHs had low concentrations, from 0.30 to 3.38 µg g–1, and presented a biogenic allocthonous origin. The PAH concentrations ranged from 0.99 to 673 ng g–1. The distribution of the alkyl homologues and the compound indices showed a clear predominance of PAHs of petrogenic origin. The chlorinated hydrocarbons presented a surface maximum, decreasing with depth to non-detectable levels. The PCB concentrations ranged from 0.18 to 7.15 ng g–1 and pesticides from 0.09 to 19.71 ng g–1. The pesticides that occurred most frequently were p,p'-DDT and its metabolites (p,p'-DDE and p,p'-DDD). Other pesticides detected were γ-chlordane and BHC isomers (α and γ). The statigraphy of the cores was carried out with molecular markers (chlorinated hydrocarbons), which were used to calculate a rate of sedimentation of 0.17 to 0.55 cm yr–1.