Oxidative coupling-type mechanism of N,N-dialkylanilines in solvent-free conditions forming crystal violet derivatives. A clay-mediated and microwave-promoted approach
In the clay-mediated reaction of N,N-disubstituted anilines using microwave radiation as an energy source in the absence of solvent, crystal violet and derivatives, diphenylmethanes, and biphenyls were isolated along with intermediates supporting an oxidative coupling-type mechanism.
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2000 |
| País: | México |
| Institución: | Universidad Nacional Autónoma de México |
| Repositorio: | Sistema de Información de la Facultad de Ciencias, UNAM |
| OAI Identifier: | oai:repositorio.fciencias.unam.mx:11154/2034 |
| Acceso en línea: | http://hdl.handle.net/11154/2034 |
| Access Level: | acceso abierto |
| Palabra clave: | Chemistry, Multidisciplinary clay dyes microwave radiation solvent-free reactions |
| Sumario: | In the clay-mediated reaction of N,N-disubstituted anilines using microwave radiation as an energy source in the absence of solvent, crystal violet and derivatives, diphenylmethanes, and biphenyls were isolated along with intermediates supporting an oxidative coupling-type mechanism. |
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