Cyclic C-F-Metal Containig Species. Solid State and Computational Examples
This article examines the results of research published be- tween 2000 and 2012, which found experimental evidence of cyclic species containing the fragment carbon-fluorine-transition metal. 25 Examples (numbered throughout this paper) with 20 different metals and a wide variety of chemical environm...
| Authors: | , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2013 |
| Country: | México |
| Institution: | Universidad Nacional Autónoma de México |
| Repository: | Redalyc-UNAM |
| OAI Identifier: | oai:redalyc.org:47527856012 |
| Online Access: | https://www.redalyc.org/articulo.oa?id=47527856012 |
| Access Level: | Open access |
| Keyword: | Química Carbon theory fluorine structure bond activation |
| Summary: | This article examines the results of research published be- tween 2000 and 2012, which found experimental evidence of cyclic species containing the fragment carbon-fluorine-transition metal. 25 Examples (numbered throughout this paper) with 20 different metals and a wide variety of chemical environments have been gathered. A similar analysis brings together almost 40 transitional states and intermediates resulting from theoretical work studying the transition metal mediated carbon-fluorine bond activation. Among other aspects, this review is useful to recognize the specific characteristics which determine whether the C-F activation process is carried out through a concerted process, a mechanism assisted by auxiliary ligands or by free radicals. |
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