Muricenones A and B: New degraded pregnanes from a gorgonian of the genus Muricea

The gorgonian Muricea sp. contains two new degraded pregnanes, muricenones A (1) and B (2), whose structures have been defined by spectroscopic analysis. The uncommon carbon framework of muricenones may be biosynthetically derived by oxidative cleavage and loss of one carbon atom of the A-ring of th...

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Bibliographic Details
Authors: Ortega, MJ, Zubia, E, Carballo, JL, Salva, J, Rodríguez, S
Format: article
Status:Published version
Publication Date:2002
Country:México
Institution:Universidad Nacional Autónoma de México
Repository:Sistema de Información de la Facultad de Ciencias, UNAM
OAI Identifier:oai:repositorio.fciencias.unam.mx:11154/2509
Online Access:http://hdl.handle.net/11154/2509
Access Level:Open access
Keyword:Chemistry, Organic
natural products
octocorals
steroids
structure elucidation
cytotoxicity
Description
Summary:The gorgonian Muricea sp. contains two new degraded pregnanes, muricenones A (1) and B (2), whose structures have been defined by spectroscopic analysis. The uncommon carbon framework of muricenones may be biosynthetically derived by oxidative cleavage and loss of one carbon atom of the A-ring of the steroidal nucleus. The new compounds, I and 2, isolated from Muricea sp., selectively inhibit the growth of the A-549 human lung carcinoma cell line. ((C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002).