Tailoring the shape of oxide complex nanostructures

The synthesis of complex nanostructures that combine materials and dimensionality, promises the ability to identify novel designs and architectures with enhanced properties that could be used in new devices. One of the building blocks in nanomaterials are nanowires, which offer several possibilities...

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Detalles Bibliográficos
Autores: Méndez Martín, María Bianchi, López, I., Alonso Orts, Manuel, Sanz, A., Nogales Díaz, Emilio, Hidalgo Alcalde, Pedro, Piqueras De Noriega, Francisco Javier
Tipo de recurso: capítulo de libro
Fecha de publicación:2017
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/19477
Acceso en línea:https://hdl.handle.net/20.500.14352/19477
Access Level:acceso abierto
Palabra clave:538.9
Ga₂O₃
Nanowires
Luminescence
Growth
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
Descripción
Sumario:The synthesis of complex nanostructures that combine materials and dimensionality, promises the ability to identify novel designs and architectures with enhanced properties that could be used in new devices. One of the building blocks in nanomaterials are nanowires, which offer several possibilities to get complex nanostructures. We present two kinds of morphologies based on oxide nanowires obtained by a thermal evaporation method. The common feature of both morphologies is a central oxide nanowire and, depending on the growth parameters, nanowires with either nanocrystallites or nano/microrods attached to the central wire are obtained. We have previously reported the fabrication of several single oxide nanowires and in particular, gallium oxide (ß-Ga₂O₃) and zinc germanate oxide (Zn₂GeO₄) nanowires. Here we report the shape evolution of these nanowires by the suitable modification of the growth parameters. The addition of tin oxide (SnO₂) to the precursors and variation of the thermal treatments duration result in the formation of the above-mentioned complex nanostructures. Structural and chemical characterizations were performed by electron microscopy techniques and Raman spectroscopy. The results shed light on the understanding of the driving mechanisms that lead to the formation of complex oxide nanostructures.