The role of surface properties in the cathodoluminescence of Zn2GeO4/SnO2 nanowire heterostructures
Herein, we report the influence of the surface conditions on the cathodoluminescence (CL) emissions from Zn_2GeO_4 nanowires and Zn_2GeO_4/SnO_2 heterostructures obtained by thermal evaporation technique. A Zn_2GeO_4 nanowire surrounded by a discontinuous shell of SnO_2 crystals composed the Zn_2GeO...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2020 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/6514 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/6514 |
| Access Level: | acceso abierto |
| Palabra clave: | 538.9 Evaporization Zinc germanate UV luminescence Nanowires Física de materiales Física del estado sólido 2211 Física del Estado Sólido |
| Sumario: | Herein, we report the influence of the surface conditions on the cathodoluminescence (CL) emissions from Zn_2GeO_4 nanowires and Zn_2GeO_4/SnO_2 heterostructures obtained by thermal evaporation technique. A Zn_2GeO_4 nanowire surrounded by a discontinuous shell of SnO_2 crystals composed the Zn_2GeO_4/SnO_2 heterostructures. Local CL measurements at different acceleration voltages allow monitoring the emission bands originated at the interface region, showing an additional deep-ultraviolet (UV) emission at 4.40 eV, which has not been previously reported. CL spectra from SnO_2 coated Zn_2GeO_4 nanowires also show this deep-UV emission. The results would confirm the presence of a shallow energy level close to the conduction band, which becomes active by passivation of Zn_2GeO_4 nanowires surface by the SnO_2 coating. |
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