Selenocystine modified screen-printed electrode as an alternative sensor for the voltammetric determination of metal ions
A novel selenium based screen-printed electrode was developed based on the immobilization of selenocystine on aryl diazonium salt monolayers anchored to a carbon-nanofiber screen-printed electrode support (SeCyst- SPCNFE). SeCyst-SPCNFE was analytically compared to a screen-printed carbon nanofiber...
| Autores: | , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2017 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2445/127716 |
| Acceso en línea: | https://hdl.handle.net/2445/127716 |
| Access Level: | acceso abierto |
| Palabra clave: | Voltametria Elèctrodes Seleni Voltammetry Electrodes Selenium |
| Sumario: | A novel selenium based screen-printed electrode was developed based on the immobilization of selenocystine on aryl diazonium salt monolayers anchored to a carbon-nanofiber screen-printed electrode support (SeCyst- SPCNFE). SeCyst-SPCNFE was analytically compared to a screen-printed carbon nanofiber electrode modified with L-Cystine (Cyst-SPCNFE) for the determination of Pb(II) and Cd(II) by stripping voltammetric techniques. Their analytical performance suggests that SeCyst-SPCNFE could be a much better alternative for metal ion determination at trace levels than Cyst-SPCNFE. The proposed electrode was successfully applied for the simultaneous voltammetric determination of trace Pb(II) and Cd(II) in a wastewater reference material with a very high reproducibility (3.2%) and good trueness (2.6%). |
|---|