Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability

[EN] Electrospun poly(vinylidene fluoride) (PVDF) fiber mats find applications in an increasing number of areas, such as battery separators, filtration and detection membranes, due to their excellent properties. However, there are limitations due to the hydrophobic nature and low surface energy of P...

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Autores: Correia, Daniela M., Ribeiro, Clarisse, Sencadas, Vitor Joao Gomes Da Silva, Botelho, G., Carabineiro, S.A.C., Lanceros-Mendez, Senentxu, Gómez Ribelles, José Luís|||0000-0001-9099-0885
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/71307
Acceso en línea:https://riunet.upv.es/handle/10251/71307
Access Level:acceso abierto
Palabra clave:Electrospun membranes
Electroactive PVDF
Oxygen plasma treatment
Surface modification
Surface wettability
Oxidation mechanism
MAQUINAS Y MOTORES TERMICOS
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repository_id_str
dc.title.none.fl_str_mv Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability
title Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability
spellingShingle Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability
Correia, Daniela M.
Electrospun membranes
Electroactive PVDF
Oxygen plasma treatment
Surface modification
Surface wettability
Oxidation mechanism
MAQUINAS Y MOTORES TERMICOS
title_short Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability
title_full Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability
title_fullStr Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability
title_full_unstemmed Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability
title_sort Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability
dc.creator.none.fl_str_mv Correia, Daniela M.
Ribeiro, Clarisse
Sencadas, Vitor Joao Gomes Da Silva
Botelho, G.
Carabineiro, S.A.C.
Lanceros-Mendez, Senentxu
Gómez Ribelles, José Luís|||0000-0001-9099-0885
author Correia, Daniela M.
author_facet Correia, Daniela M.
Ribeiro, Clarisse
Sencadas, Vitor Joao Gomes Da Silva
Botelho, G.
Carabineiro, S.A.C.
Lanceros-Mendez, Senentxu
Gómez Ribelles, José Luís|||0000-0001-9099-0885
author_role author
author2 Ribeiro, Clarisse
Sencadas, Vitor Joao Gomes Da Silva
Botelho, G.
Carabineiro, S.A.C.
Lanceros-Mendez, Senentxu
Gómez Ribelles, José Luís|||0000-0001-9099-0885
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Termodinámica Aplicada
Centro de Biomateriales e Ingeniería Tisular
Escuela Técnica Superior de Ingeniería Industrial
Ministerio de Economía y Competitividad
European Cooperation in Science and Technology
European Regional Development Fund
Instituto de Salud Carlos III
Ministerio de Ciencia e Innovación
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Electrospun membranes
Electroactive PVDF
Oxygen plasma treatment
Surface modification
Surface wettability
Oxidation mechanism
MAQUINAS Y MOTORES TERMICOS
topic Electrospun membranes
Electroactive PVDF
Oxygen plasma treatment
Surface modification
Surface wettability
Oxidation mechanism
MAQUINAS Y MOTORES TERMICOS
description [EN] Electrospun poly(vinylidene fluoride) (PVDF) fiber mats find applications in an increasing number of areas, such as battery separators, filtration and detection membranes, due to their excellent properties. However, there are limitations due to the hydrophobic nature and low surface energy of PVDF. In this work, oxygen plasma treatment has been applied in order to modify the surface wettability of PVDF fiber mats and superhydrophilic PVDF electrospun membranes have been obtained. Further, plasma treatment does not significantly influences fiber average size (similar to 400 +/- 200 nm), morphology, electroacfive beta-phase content (similar to 80-85%) or the degree of crystallinity (X-c of 42 +/- 2%), allowing to maintain the excellent physical-chemical characteristics of PVDF. Plasma treatment mainly induces surface chemistry modifications, such as the introduction of oxygen and release of fluorine atoms that significantly changes polymer membrane wettability by a reduction of the contact angle of the polymer fibers and an overall decrease of the surface tension of the membranes.
publishDate 2015
dc.date.none.fl_str_mv 2015
2015-08-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/71307
url https://riunet.upv.es/handle/10251/71307
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Cooperation in Science and Technology https://doi.org/10.13039/501100000921 MP1003 European Scientific Network for Artificial Muscles (ESNAM)
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2013-46467-C4-1-R ESTIMULACION MECANICA LOCAL DE CELULAS MESENQUIMALES DE CARA A SU DIFERENCIACION OSTEOGENICA Y CONDROGENICA EN MEDICINA REGENERATIVA
European Cooperation in Science and Technology https://doi.org/10.13039/501100000921 MP1206 Electrospun nano-fibres for bio inspired composite materials and innovative industrial applications
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 SFRH SFRH%2FBD%2F82411%2F2011 SCAFFOLDS TRIDIMENSIONAIS BASEADOS EM NNANOFIBRAS ELECTROACTIVAS BIODEGRADÁVEIS PARA APLICAÇÃO EM ENGENHARIA DE TECIDOS
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 SFRH SFRH%2FBPD%2F90870%2F2012 TAILORING ELECTRO-MECHANICALLY ACTIVE MATERIALS FOR TISSUE ENGINEERING APPLICATIONS
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 SFRH SFRH%2FBPD%2F64958%2F2009 ENGINEERING TISSUES WITH BACTERIAL CELLULOSE
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 SFRH SFRH%2FBSAB%2F1381%2F2013 STOCK EXCHANGES IN HISTORICAL PERSPECTIVE
European Cooperation in Science and Technology https://doi.org/10.13039/501100000921 MP1301 New Generation Biomimetic and Customized Implants for Bone Engineering
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 5876-PPCDTI 109368 “Smart joint implants using bionanocomposites-(SIMBIO)”
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 5876-PPCDTI 112574 A novel pressure sensor network system for static and dynamic measurement. Application to the limb
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 PEST-C%2FFIS%2FUI607%2F2011
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 PEST-C%2FQUI%2FUIO686%2F2013
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 NORTE-07-0124-FEDER-000037 Matepro - Optimizing Materials and Processes
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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spelling Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettabilityCorreia, Daniela M.Ribeiro, ClarisseSencadas, Vitor Joao Gomes Da SilvaBotelho, G.Carabineiro, S.A.C.Lanceros-Mendez, SenentxuGómez Ribelles, José Luís|||0000-0001-9099-0885Electrospun membranesElectroactive PVDFOxygen plasma treatmentSurface modificationSurface wettabilityOxidation mechanismMAQUINAS Y MOTORES TERMICOS[EN] Electrospun poly(vinylidene fluoride) (PVDF) fiber mats find applications in an increasing number of areas, such as battery separators, filtration and detection membranes, due to their excellent properties. However, there are limitations due to the hydrophobic nature and low surface energy of PVDF. In this work, oxygen plasma treatment has been applied in order to modify the surface wettability of PVDF fiber mats and superhydrophilic PVDF electrospun membranes have been obtained. Further, plasma treatment does not significantly influences fiber average size (similar to 400 +/- 200 nm), morphology, electroacfive beta-phase content (similar to 80-85%) or the degree of crystallinity (X-c of 42 +/- 2%), allowing to maintain the excellent physical-chemical characteristics of PVDF. Plasma treatment mainly induces surface chemistry modifications, such as the introduction of oxygen and release of fluorine atoms that significantly changes polymer membrane wettability by a reduction of the contact angle of the polymer fibers and an overall decrease of the surface tension of the membranes.This work is funded by FEDER funds through the "Programa Operacional Fatores de Competitividade - COMPETE" and by national funds arranged by FCT - Fundacao para a Ciencia e a Tecnologia, project references NANO/NMed-SD/0156/2007, PTDC/CTM-NAN/112574/2009, PEST-C/FIS/UI607/2011 and PEST-C/QUI/UIO686/2013. The authors also thank funding from Matepro - Optimizing Materials and Processes", ref. NORTE-07-0124-FEDER-000037", co-funded by the "Programa Operacional Regional do Norte" (ON.2-O Novo Norte), under the "Quadro de Referencia Estrategico Nacional" (QREN), through the "Fundo Europeu de Desenvolvimento Regional" (FEDER). The authors also thank support from the COST Action MP1003, 2010 'European Scientific Network for Artificial Muscles', MP1206 "Electrospun Nano-fibres for bio inspired composite materials and innovative industrial applications" and MP1301 "New Generation Biomimetic and Customized Implants for Bone Engineering". DMC, CR, VS and SACC thank the FCT for the SFRH/BD/82411/2011, SFRH/BPD/90870/2012, SFRH/BPD/64958/2009 and Investigator FCT IF/1381/2013 grants, respectively. JLGR acknowledges the support of Ministerio de Economia y Competitividad, MINECO, through the MAT2013-46467-C4-1-R project. CIBER-BBN is an initiative funded by the VI National R&D&i Plan 2008-2011, Iniciativa Ingenio 2010, Consolider Program, CIBER Actions and financed by the Instituto de Salud Carlos III with assistance from the European Regional Development Fund. Dr. Carlos M. Sa (CEMUP) is acknowledged for assistance with XPS analyses.ElsevierDepartamento de Termodinámica AplicadaCentro de Biomateriales e Ingeniería TisularEscuela Técnica Superior de Ingeniería IndustrialMinisterio de Economía y CompetitividadEuropean Cooperation in Science and TechnologyEuropean Regional Development FundInstituto de Salud Carlos IIIMinisterio de Ciencia e InnovaciónRepositorio Institucional de la Universitat Politècnica de València Riunet20152015-08-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/71307reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengEuropean Cooperation in Science and Technology https://doi.org/10.13039/501100000921 MP1003 European Scientific Network for Artificial Muscles (ESNAM)Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2013-46467-C4-1-R ESTIMULACION MECANICA LOCAL DE CELULAS MESENQUIMALES DE CARA A SU DIFERENCIACION OSTEOGENICA Y CONDROGENICA EN MEDICINA REGENERATIVAEuropean Cooperation in Science and Technology https://doi.org/10.13039/501100000921 MP1206 Electrospun nano-fibres for bio inspired composite materials and innovative industrial applicationsFundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 SFRH SFRH%2FBD%2F82411%2F2011 SCAFFOLDS TRIDIMENSIONAIS BASEADOS EM NNANOFIBRAS ELECTROACTIVAS BIODEGRADÁVEIS PARA APLICAÇÃO EM ENGENHARIA DE TECIDOSFundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 SFRH SFRH%2FBPD%2F90870%2F2012 TAILORING ELECTRO-MECHANICALLY ACTIVE MATERIALS FOR TISSUE ENGINEERING APPLICATIONSFundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 SFRH SFRH%2FBPD%2F64958%2F2009 ENGINEERING TISSUES WITH BACTERIAL CELLULOSEFundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 SFRH SFRH%2FBSAB%2F1381%2F2013 STOCK EXCHANGES IN HISTORICAL PERSPECTIVEEuropean Cooperation in Science and Technology https://doi.org/10.13039/501100000921 MP1301 New Generation Biomimetic and Customized Implants for Bone EngineeringFundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 5876-PPCDTI 109368 “Smart joint implants using bionanocomposites-(SIMBIO)”Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 5876-PPCDTI 112574 A novel pressure sensor network system for static and dynamic measurement. Application to the limbFundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 PEST-C%2FFIS%2FUI607%2F2011Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 PEST-C%2FQUI%2FUIO686%2F2013Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 NORTE-07-0124-FEDER-000037 Matepro - Optimizing Materials and Processesopen accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/713072026-06-13T07:49:27Z
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