Stapled helical: o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity

ortho-Oligo(phenylene)ethynylenes (o-OPEs) stapled with enantiopure 2,3-dihydroxybutane diethers have highly intense circular dichroism (CD) spectra and excellent circular polarized luminescence (CPL) responses (glum values up to 1.1 × 10-2), which are consistent with homochiral helically folded str...

Descripción completa

Detalles Bibliográficos
Autores: Morcillo, S. F., Miguel, D., Álvarez de Cienfuegos, Luis, Justicia, José, Abbate, Sergio, Castiglioni, E., Bour, C., Ribagorda Lobera, María, Cárdenas, D.J., Paredes, J.M., Crovetto, L., Choquesillo- Lazarte, D., Mota, A.J., Carreño García, Carmen, Longhi, G., Cuerva Carvajal, Juan Manuel
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/677234
Acceso en línea:http://hdl.handle.net/10486/677234
https://dx.doi.org/10.1039/c6sc01808d
Access Level:acceso abierto
Palabra clave:Luminescence
Silver
Circular polarized
Enantiopure
Foldamers
Química
id ES_fa5694b1c2cd2af670d4da91ce823cb0
oai_identifier_str oai:repositorio.uam.es:10486/677234
network_acronym_str ES
network_name_str España
repository_id_str
spelling Stapled helical: o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivityMorcillo, S. F.Miguel, D.Álvarez de Cienfuegos, LuisJusticia, JoséAbbate, SergioCastiglioni, E.Bour, C.Ribagorda Lobera, MaríaCárdenas, D.J.Paredes, J.M.Crovetto, L.Choquesillo- Lazarte, D.Mota, A.J.Carreño García, CarmenLonghi, G.Cuerva Carvajal, Juan ManuelLuminescenceSilverCircular polarizedEnantiopureFoldamersQuímicaortho-Oligo(phenylene)ethynylenes (o-OPEs) stapled with enantiopure 2,3-dihydroxybutane diethers have highly intense circular dichroism (CD) spectra and excellent circular polarized luminescence (CPL) responses (glum values up to 1.1 × 10-2), which are consistent with homochiral helically folded structures. In the presence of Ag(i), a change in the CPL emission is observed, representing the first example of CPL active small organic molecular emitters, which can be modulated by carbophilic interactions in a reversible mannerWe thank Intramural CSIC project (201530E01) and MICINN (FEDER funded Grants CTQ2014-53598, CTQ2011-24783 and CTQ2014-53894-R) for financial support.Royal Society of ChemistryDepartamento de Química OrgánicaFacultad de Ciencias20162016-05-16research articlehttp://purl.org/coar/resource_type/c_2df8fbb1VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/677234https://dx.doi.org/10.1039/c6sc01808dreponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/6772342026-06-23T12:46:27Z
dc.title.none.fl_str_mv Stapled helical: o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity
title Stapled helical: o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity
spellingShingle Stapled helical: o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity
Morcillo, S. F.
Luminescence
Silver
Circular polarized
Enantiopure
Foldamers
Química
title_short Stapled helical: o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity
title_full Stapled helical: o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity
title_fullStr Stapled helical: o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity
title_full_unstemmed Stapled helical: o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity
title_sort Stapled helical: o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity
dc.creator.none.fl_str_mv Morcillo, S. F.
Miguel, D.
Álvarez de Cienfuegos, Luis
Justicia, José
Abbate, Sergio
Castiglioni, E.
Bour, C.
Ribagorda Lobera, María
Cárdenas, D.J.
Paredes, J.M.
Crovetto, L.
Choquesillo- Lazarte, D.
Mota, A.J.
Carreño García, Carmen
Longhi, G.
Cuerva Carvajal, Juan Manuel
author Morcillo, S. F.
author_facet Morcillo, S. F.
Miguel, D.
Álvarez de Cienfuegos, Luis
Justicia, José
Abbate, Sergio
Castiglioni, E.
Bour, C.
Ribagorda Lobera, María
Cárdenas, D.J.
Paredes, J.M.
Crovetto, L.
Choquesillo- Lazarte, D.
Mota, A.J.
Carreño García, Carmen
Longhi, G.
Cuerva Carvajal, Juan Manuel
author_role author
author2 Miguel, D.
Álvarez de Cienfuegos, Luis
Justicia, José
Abbate, Sergio
Castiglioni, E.
Bour, C.
Ribagorda Lobera, María
Cárdenas, D.J.
Paredes, J.M.
Crovetto, L.
Choquesillo- Lazarte, D.
Mota, A.J.
Carreño García, Carmen
Longhi, G.
Cuerva Carvajal, Juan Manuel
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Química Orgánica
Facultad de Ciencias
dc.subject.none.fl_str_mv Luminescence
Silver
Circular polarized
Enantiopure
Foldamers
Química
topic Luminescence
Silver
Circular polarized
Enantiopure
Foldamers
Química
description ortho-Oligo(phenylene)ethynylenes (o-OPEs) stapled with enantiopure 2,3-dihydroxybutane diethers have highly intense circular dichroism (CD) spectra and excellent circular polarized luminescence (CPL) responses (glum values up to 1.1 × 10-2), which are consistent with homochiral helically folded structures. In the presence of Ag(i), a change in the CPL emission is observed, representing the first example of CPL active small organic molecular emitters, which can be modulated by carbophilic interactions in a reversible manner
publishDate 2016
dc.date.none.fl_str_mv 2016
2016-05-16
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/677234
https://dx.doi.org/10.1039/c6sc01808d
url http://hdl.handle.net/10486/677234
https://dx.doi.org/10.1039/c6sc01808d
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869425201659248640
score 15,300719

Similares en LA Referencia