Impact of short-chain alcohols on carbonyl emissions in dual-fuel compression ignition engines

This study investigated the impact of methanol and ethanol on carbonyl emissions from a single-cylinder diesel engine operating under dual-fuel mode. Fourteen carbonyl compounds were investigated, with formaldehyde and acetaldehyde dominating the emissions. Moderate amounts of alcohol did not signif...

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Detalhes bibliográficos
Autores: Patiño-Camino , Rayda, Cova-Bonillo , Alexis, Villanueva García, Florentina, Ramos Diezma, Ángel, Domínguez , Victor Manuel, Rodríguez Fernández, José, Hernández Adrover, Juan José
Formato: artículo
Fecha de publicación:2025
País:España
Recursos:Universidad de Castilla-La Mancha
Repositorio:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/43981
Acesso em linha:https://doi.org/10.1016/j.fuel.2025.134916
https://hdl.handle.net/10578/43981
Access Level:acceso abierto
Palavra-chave:Carbonyls emission
Dual-fuel CI combustion
Light alcohols
Descrição
Resumo:This study investigated the impact of methanol and ethanol on carbonyl emissions from a single-cylinder diesel engine operating under dual-fuel mode. Fourteen carbonyl compounds were investigated, with formaldehyde and acetaldehyde dominating the emissions. Moderate amounts of alcohol did not significantly affect specific carbonyl emissions. However, higher ethanol concentrations increased carbonyl emissions, especially when using ethanol and biodiesel. Specific reactivity, a measure of the potential impact of pollutants on atmospheric ozone formation, was quite similar for all fueling conditions tested, despite some of these conditions notably increased total carbonyl emissions. Thus, contrary to expectations, dual-fuel mode had a minimal effect on specific reactivity, even at high alcohol substitution ratios. This result suggests that using light alcohols in dual-fuel CI engines does not increase the atmospheric reactivity of exhaust gases, and their use in decarbonizing heavy-duty CI engines seems viable, even considering future emission standards for unregulated emissions like carbonyls.