Stereoselective oxidation of titanium(IV) enolates with oxygen

A novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A highly stereoselective oxidation of titanium(IV) enolates from chiral N-acyloxazolidinones is performed with oxygen under simple experimental conditions that do not require any reducing steps. The su...

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Detalles Bibliográficos
Autores: Gómez Palomino, Alejandro, Romea, Pedro, Urpí Tubella, Fèlix
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2018
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/128156
Acceso en línea:https://hdl.handle.net/2445/128156
Access Level:acceso abierto
Palabra clave:Titani
Estereoquímica
Quiralitat
Titanium
Stereochemistry
Chirality
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spelling Stereoselective oxidation of titanium(IV) enolates with oxygenGómez Palomino, AlejandroRomea, PedroUrpí Tubella, FèlixTitaniEstereoquímicaQuiralitatTitaniumStereochemistryChiralityA novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A highly stereoselective oxidation of titanium(IV) enolates from chiral N-acyloxazolidinones is performed with oxygen under simple experimental conditions that do not require any reducing steps. The success of this approach depends on the biradical character of titanium(IV) enolates.Georg Thieme Verlag2018info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://hdl.handle.net/2445/128156Articles publicats en revistes (Química Inorgànica i Orgànica)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésVersió postprint del document publicat a: https://doi.org/10.1055/s-0037-1609966Synthesis. Journal of Synthetic Organic Chemistry, 2018, vol. 50, num. 14, p. 2721-2726https://doi.org/10.1055/s-0037-1609966(c) Georg Thieme Verlag, 2018info:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/1281562026-05-27T06:46:51Z
dc.title.none.fl_str_mv Stereoselective oxidation of titanium(IV) enolates with oxygen
title Stereoselective oxidation of titanium(IV) enolates with oxygen
spellingShingle Stereoselective oxidation of titanium(IV) enolates with oxygen
Gómez Palomino, Alejandro
Titani
Estereoquímica
Quiralitat
Titanium
Stereochemistry
Chirality
title_short Stereoselective oxidation of titanium(IV) enolates with oxygen
title_full Stereoselective oxidation of titanium(IV) enolates with oxygen
title_fullStr Stereoselective oxidation of titanium(IV) enolates with oxygen
title_full_unstemmed Stereoselective oxidation of titanium(IV) enolates with oxygen
title_sort Stereoselective oxidation of titanium(IV) enolates with oxygen
dc.creator.none.fl_str_mv Gómez Palomino, Alejandro
Romea, Pedro
Urpí Tubella, Fèlix
author Gómez Palomino, Alejandro
author_facet Gómez Palomino, Alejandro
Romea, Pedro
Urpí Tubella, Fèlix
author_role author
author2 Romea, Pedro
Urpí Tubella, Fèlix
author2_role author
author
dc.subject.none.fl_str_mv Titani
Estereoquímica
Quiralitat
Titanium
Stereochemistry
Chirality
topic Titani
Estereoquímica
Quiralitat
Titanium
Stereochemistry
Chirality
description A novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A highly stereoselective oxidation of titanium(IV) enolates from chiral N-acyloxazolidinones is performed with oxygen under simple experimental conditions that do not require any reducing steps. The success of this approach depends on the biradical character of titanium(IV) enolates.
publishDate 2018
dc.date.none.fl_str_mv 2018
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/128156
url https://hdl.handle.net/2445/128156
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: https://doi.org/10.1055/s-0037-1609966
Synthesis. Journal of Synthetic Organic Chemistry, 2018, vol. 50, num. 14, p. 2721-2726
https://doi.org/10.1055/s-0037-1609966
dc.rights.none.fl_str_mv (c) Georg Thieme Verlag, 2018
info:eu-repo/semantics/openAccess
rights_invalid_str_mv (c) Georg Thieme Verlag, 2018
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Georg Thieme Verlag
publisher.none.fl_str_mv Georg Thieme Verlag
dc.source.none.fl_str_mv Articles publicats en revistes (Química Inorgànica i Orgànica)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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