Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders

The reaction of the chiral dipeptide glycyl-L(S)-glutamate with Co<sup>II</sup> ions produces chiral ladders that can be used as rigid 1D building units. Spatial separation of these building units with linkers of different lengths allows the engineering of homochiral porous MOFs with enh...

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Autores: Stylianou, Kyriakos C.|||0000-0003-1670-0020, Gómez, Laura|||0000-0003-3719-6855, Imaz, Inhar|||0000-0002-0278-1141, Verdugo-Escamilla, Cristóbal|||0000-0003-2345-8359, Ribas, Xavi|||0000-0002-2850-4409, Maspoch Comamala, Daniel|||0000-0003-1325-9161
Formato: artículo
Fecha de publicación:2015
País:España
Recursos:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:307862
Acesso em linha:https://ddd.uab.cat/record/307862
https://dx.doi.org/urn:doi:10.1002/chem.201501315
Access Level:acceso abierto
Palavra-chave:Metal organic frameworks
Peptides
Chiral
Porous
Enantioselective separation
Enantiomeric excess
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spelling Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide LaddersTuning the Pore Size for Enantioselective AdsorptionStylianou, Kyriakos C.|||0000-0003-1670-0020Gómez, Laura|||0000-0003-3719-6855Imaz, Inhar|||0000-0002-0278-1141Verdugo-Escamilla, Cristóbal|||0000-0003-2345-8359Ribas, Xavi|||0000-0002-2850-4409Maspoch Comamala, Daniel|||0000-0003-1325-9161Metal organic frameworksPeptidesChiralPorousEnantioselective separationEnantiomeric excessThe reaction of the chiral dipeptide glycyl-L(S)-glutamate with Co<sup>II</sup> ions produces chiral ladders that can be used as rigid 1D building units. Spatial separation of these building units with linkers of different lengths allows the engineering of homochiral porous MOFs with enhanced pore sizes, pore volumes, and surface areas. This strategy enables the synthesis of a family of isoreticular MOFs, in which the pore size dictates the enantioselective adsorption of chiral molecules (in terms of their size and enantiomeric excess). 22015-01-0120152015-01-01Articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/307862https://dx.doi.org/urn:doi:10.1002/chem.201501315reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2012-30994European Commission https://doi.org/10.13039/501100000780 300390Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295open accesshttp://purl.org/coar/access_right/c_abf2Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.https://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:3078622026-06-06T12:50:31Z
dc.title.none.fl_str_mv Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders
Tuning the Pore Size for Enantioselective Adsorption
title Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders
spellingShingle Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders
Stylianou, Kyriakos C.|||0000-0003-1670-0020
Metal organic frameworks
Peptides
Chiral
Porous
Enantioselective separation
Enantiomeric excess
title_short Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders
title_full Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders
title_fullStr Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders
title_full_unstemmed Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders
title_sort Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders
dc.creator.none.fl_str_mv Stylianou, Kyriakos C.|||0000-0003-1670-0020
Gómez, Laura|||0000-0003-3719-6855
Imaz, Inhar|||0000-0002-0278-1141
Verdugo-Escamilla, Cristóbal|||0000-0003-2345-8359
Ribas, Xavi|||0000-0002-2850-4409
Maspoch Comamala, Daniel|||0000-0003-1325-9161
author Stylianou, Kyriakos C.|||0000-0003-1670-0020
author_facet Stylianou, Kyriakos C.|||0000-0003-1670-0020
Gómez, Laura|||0000-0003-3719-6855
Imaz, Inhar|||0000-0002-0278-1141
Verdugo-Escamilla, Cristóbal|||0000-0003-2345-8359
Ribas, Xavi|||0000-0002-2850-4409
Maspoch Comamala, Daniel|||0000-0003-1325-9161
author_role author
author2 Gómez, Laura|||0000-0003-3719-6855
Imaz, Inhar|||0000-0002-0278-1141
Verdugo-Escamilla, Cristóbal|||0000-0003-2345-8359
Ribas, Xavi|||0000-0002-2850-4409
Maspoch Comamala, Daniel|||0000-0003-1325-9161
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Metal organic frameworks
Peptides
Chiral
Porous
Enantioselective separation
Enantiomeric excess
topic Metal organic frameworks
Peptides
Chiral
Porous
Enantioselective separation
Enantiomeric excess
description The reaction of the chiral dipeptide glycyl-L(S)-glutamate with Co<sup>II</sup> ions produces chiral ladders that can be used as rigid 1D building units. Spatial separation of these building units with linkers of different lengths allows the engineering of homochiral porous MOFs with enhanced pore sizes, pore volumes, and surface areas. This strategy enables the synthesis of a family of isoreticular MOFs, in which the pore size dictates the enantioselective adsorption of chiral molecules (in terms of their size and enantiomeric excess).
publishDate 2015
dc.date.none.fl_str_mv 2
2015-01-01
2015
2015-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/307862
https://dx.doi.org/urn:doi:10.1002/chem.201501315
url https://ddd.uab.cat/record/307862
https://dx.doi.org/urn:doi:10.1002/chem.201501315
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2012-30994
European Commission https://doi.org/10.13039/501100000780 300390
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.811543

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