Measuring specific retention volumes in capillary gas chromatography with improved accuracy and precision

9 pages, 2 figures, 7 tables

Detalles Bibliográficos
Autores: Quintanilla-López, Jesús Eduardo, Lebrón-Aguilar, Rosa, Tello, Ana María, García-Domínguez, José Antonio
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:1996
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/413554
Acceso en línea:http://hdl.handle.net/10261/413554
https://api.elsevier.com/content/abstract/scopus_id/0030048865
Access Level:acceso abierto
Palabra clave:Retention volume
Specific
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spelling Measuring specific retention volumes in capillary gas chromatography with improved accuracy and precisionQuintanilla-López, Jesús EduardoLebrón-Aguilar, RosaTello, Ana MaríaGarcía-Domínguez, José AntonioRetention volumeSpecific9 pages, 2 figures, 7 tablesThe specific retention volume (V(g)), which has traditionally been determined in gas chromatography using long, heavily loaded packed columns, should produce better, more reliable values if capillary columns are used. However, the smaller dimensions of some of the parameters involved introduces additional sources of error which have been overcome with a recently proposed equation. A careful consideration of the sources of error involved has been carried out using both the traditional and the new equations. The conclusion drawn is that the new equation will produce reliable V(g) values with expected errors (1%) lower than those expected from packed columns (2%) using the traditional equation.This work was carried out with the financial assistance of the Dirección General de Investigación Cientifica y Técnica of Spain, under Projects PB91-0077 and PB94-0218. We are particularly grateful to Q. Dai, who provided data on the density of the stationary phase with carefully performed experiments.Peer reviewedElsevierDirección General de Investigación Científica y Técnica, DGICT (España)#NODATA##NODATA##NODATA##NODATA#Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202620261996info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/413554https://api.elsevier.com/content/abstract/scopus_id/0030048865reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI//PB91-0077info:eu-repo/grantAgreement/AEI//PB94-0218https://doi.org/10.1016/0021-9673(95)00812-8Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/4135542026-05-22T06:33:51Z
dc.title.none.fl_str_mv Measuring specific retention volumes in capillary gas chromatography with improved accuracy and precision
title Measuring specific retention volumes in capillary gas chromatography with improved accuracy and precision
spellingShingle Measuring specific retention volumes in capillary gas chromatography with improved accuracy and precision
Quintanilla-López, Jesús Eduardo
Retention volume
Specific
title_short Measuring specific retention volumes in capillary gas chromatography with improved accuracy and precision
title_full Measuring specific retention volumes in capillary gas chromatography with improved accuracy and precision
title_fullStr Measuring specific retention volumes in capillary gas chromatography with improved accuracy and precision
title_full_unstemmed Measuring specific retention volumes in capillary gas chromatography with improved accuracy and precision
title_sort Measuring specific retention volumes in capillary gas chromatography with improved accuracy and precision
dc.creator.none.fl_str_mv Quintanilla-López, Jesús Eduardo
Lebrón-Aguilar, Rosa
Tello, Ana María
García-Domínguez, José Antonio
author Quintanilla-López, Jesús Eduardo
author_facet Quintanilla-López, Jesús Eduardo
Lebrón-Aguilar, Rosa
Tello, Ana María
García-Domínguez, José Antonio
author_role author
author2 Lebrón-Aguilar, Rosa
Tello, Ana María
García-Domínguez, José Antonio
author2_role author
author
author
dc.contributor.none.fl_str_mv Dirección General de Investigación Científica y Técnica, DGICT (España)
#NODATA#
#NODATA#
#NODATA#
#NODATA#
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Retention volume
Specific
topic Retention volume
Specific
description 9 pages, 2 figures, 7 tables
publishDate 1996
dc.date.none.fl_str_mv 1996
2026
2026
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/413554
https://api.elsevier.com/content/abstract/scopus_id/0030048865
url http://hdl.handle.net/10261/413554
https://api.elsevier.com/content/abstract/scopus_id/0030048865
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI//PB91-0077
info:eu-repo/grantAgreement/AEI//PB94-0218
https://doi.org/10.1016/0021-9673(95)00812-8
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
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instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
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