Synthesis and characterization of three new Cu(II) paddle-wheel compounds with 1,3-benzodioxole-5-carboxylic acid
Three different paddle wheel compounds have been synthesized, each one via a different synthetic pathway. The first method is the reaction of Cu(MeCO2)2 H2O with 1,3-benzodioxole-5-carboxylic acid (Piperonylic acid, HPip) in a MeOH solution, yielding [Cu(m-Pip)2(MeOH)]2 (1). The second method is the...
| Autores: | , , , , , |
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| Tipo de documento: | artigo |
| Estado: | Versión aceptada para publicación |
| Data de publicação: | 2019 |
| País: | España |
| Recursos: | Universidad de Barcelona |
| Repositório: | Dipòsit Digital de la UB |
| OAI Identifier: | oai:diposit.ub.edu:2445/161362 |
| Acesso em linha: | https://hdl.handle.net/2445/161362 |
| Access Level: | Acceso aberto |
| Palavra-chave: | Estructura cristal·lina (Sòlids) Layer structure (Solids) |
| Resumo: | Three different paddle wheel compounds have been synthesized, each one via a different synthetic pathway. The first method is the reaction of Cu(MeCO2)2 H2O with 1,3-benzodioxole-5-carboxylic acid (Piperonylic acid, HPip) in a MeOH solution, yielding [Cu(m-Pip)2(MeOH)]2 (1). The second method is the transformation of the heteroleptic core paddle-wheel compound [Cu(m-MeCO2)(m-Pip)(MeOH)]2 into the homoleptic core paddle-wheel [Cu(m-Pip)2(DMSO)]2 2DMSO (2). Lastly, the third method is the substitution of the solvent molecule (DMF) present in the molecular array [Cu(m-Pip)2(DMF)]2 by 2-benzylpyridine (2-Bzpy) ligand, resulting in [Cu(m-Pip)2(2-Bzpy)]2 2.5MeOH H2O (3a). All compounds are characterized via EA, PXRD, ATR-FTIR, Far-IR and UV-Vis spectroscopy. For all three compounds, the X-ray crystal structure has been determined and their extended structures are discussed. Finally, TG/DTA measurements have been recorded. |
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