Synthesis, crystal structure and magnetic properties of a Cu(II) paddle-wheel complex with mixed bridges
The synthesis and characterization of a mixed carboxylate paddle-wheel copper complex, with formula [Cu(μ- Pip)(μ-MeCO2)(MeOH)]2 (Pip = piperonylate or 1,3-benzodioxole-5-carboxylate and MeCO2 = acetate), is here reported. The described compound is a binuclear complex, each pair of similar carboxyla...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2016 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2445/164364 |
| Acceso en línea: | https://hdl.handle.net/2445/164364 |
| Access Level: | acceso abierto |
| Palabra clave: | Estructura cristal·lina (Sòlids) Coure Layer structure (Solids) Copper |
| Sumario: | The synthesis and characterization of a mixed carboxylate paddle-wheel copper complex, with formula [Cu(μ- Pip)(μ-MeCO2)(MeOH)]2 (Pip = piperonylate or 1,3-benzodioxole-5-carboxylate and MeCO2 = acetate), is here reported. The described compound is a binuclear complex, each pair of similar carboxylate ligands occupyingmutually trans bridging positions,while the methanol occupies the apical positions. The dimers are arranged into 2D layers in the bc plane through a network of O-H⋯O hydrogen bonds established between themethanol and the acetate ligand. Magnetic studies showed a strong antiferromagnetic Cu⋯Cu interaction (J = −308 cm−1), in agreement with the presence of four μ-κO-κO′ carboxylates bridging the metallic centers in the binuclear complex. |
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