Wafer-Scale Synthesis of Topological Insulator Sb2Te3 Thin Films

Recently, metal-organic chemical vapor deposition (MOCVD) has been proven successful to grow topological insulators such as antimony telluride (Sb<inf>2</inf>Te<inf>3</inf>), with their use as efficient spin-charge converters at room temperature also being reported. On the ot...

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Detalles Bibliográficos
Autores: Shafiei, Ali, Fathi Hafshejani, Ahmad, Ahmed, Rehab M.G., Lamperti, Alessio, Longo, Emanuele, Locatelli, Lorenzo, Martella, Christian, Molle, Alessandro, Tallarida, Graziella, Zucchetti, Carlo, Wiemer, Claudia, Longo, Massimo, Mantovan, Roberto
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/392456
Acceso en línea:http://hdl.handle.net/10261/392456
https://api.elsevier.com/content/abstract/scopus_id/85216801301
Access Level:acceso abierto
Palabra clave:Chalcogenides
Magnetotransport
MOCVD
Spintronics
Topological insulators
Weak antilocalization
Descripción
Sumario:Recently, metal-organic chemical vapor deposition (MOCVD) has been proven successful to grow topological insulators such as antimony telluride (Sb<inf>2</inf>Te<inf>3</inf>), with their use as efficient spin-charge converters at room temperature also being reported. On the other hand, a wafer-scale synthesis of Sb<inf>2</inf>Te<inf>3</inf> thin films showing clear-cut electrical conduction driven by topologically protected surface states is still missing. Within this work, the growth of Sb<inf>2</inf>Te<inf>3</inf> thin films with variable thicknesses over 4-inch (4″) wafer-scale Si(111) substrates as conducted via MOCVD is reported. By performing magnetoconductance measurements, weak antilocalization phenomena are detected over the whole 4″ area, thus proving the possibility to produce wafer-scale Sb<inf>2</inf>Te<inf>3</inf> topological insulator thin films. Furthermore, comprehensive information on the variability of the functional properties of Sb<inf>2</inf>Te<inf>3</inf> thin films with their morphological, chemical, and structural properties, as probed by scanning electron microscopy, X-ray diffraction/reflectivity, atomic force microscopy, Raman spectroscopy, time-of-flight secondary ion mass spectrometry, and energy-dispersive X-ray analyses is reported. This work provides a breakthrough for the technology scale-up of these novel materials to be employed in future spintronic devices as well as applications in nanoelectronics, thermoelectrics, and quantum computing.