Influence of doping and controlled sn charge state on the properties and performance of SnO nanoparticles as anodes in li-ion batteries

Li-ion batteries (LiB) play nowadays a major role in several technological fields. In addition to enhanced high capacity and long cyclability, some other issues regarding safety, materials sustainability, and low cost remain unsolved. Tin oxide (SnO_2) presents several of those advantages as an anod...

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Autores: Vázquez López, Antonio, Maestre Varea, David, Ramírez Castellanos, Julio, González Calbet, José María, Pís, Igor, Nappini, Silvia, Yuca, Neslihan, Cremades Rodríguez, Ana Isabel
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/6607
Acceso en línea:https://hdl.handle.net/20.500.14352/6607
Access Level:acceso abierto
Palabra clave:538.9
Doped SnO_2
Electrochemical performance
Luminescence properties
Resonant-photoemission
Hydrothermal synthesis
Optical-properties
Lithium
Composite
Fe
Ferromagnetism
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
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oai_identifier_str oai:docta.ucm.es:20.500.14352/6607
network_acronym_str ES
network_name_str España
repository_id_str
spelling Influence of doping and controlled sn charge state on the properties and performance of SnO nanoparticles as anodes in li-ion batteriesVázquez López, AntonioMaestre Varea, DavidRamírez Castellanos, JulioGonzález Calbet, José MaríaPís, IgorNappini, SilviaYuca, NeslihanCremades Rodríguez, Ana Isabel538.9Doped SnO_2Electrochemical performanceLuminescence propertiesResonant-photoemissionHydrothermal synthesisOptical-propertiesLithiumCompositeFeFerromagnetismFísica de materialesFísica del estado sólido2211 Física del Estado SólidoLi-ion batteries (LiB) play nowadays a major role in several technological fields. In addition to enhanced high capacity and long cyclability, some other issues regarding safety, materials sustainability, and low cost remain unsolved. Tin oxide (SnO_2) presents several of those advantages as an anode material; however, some aspects still require to be investigated such as capacity fading over cycles. Herein, tin oxide nanoparticle-based anodes have been tested, showing high capacities and a significant cyclability over more than 150 cycles. A complementary strategy introducing doping elements such as Li and Ni during the synthesis by hydrolysis has been also evaluated versus the use of undoped materials, in order to assess the dependence on SnO_2 quality and properties of battery performance. Diverse aspects such as the Sn charge state in the synthesized nanoparticles, the variable incorporation of dopants, and the structure of defects have been considered in the understanding of the obtained capacity.American Chemical SocietyUniversidad Complutense de Madrid20202020-08-2720202020-08-27journal articlehttp://purl.org/coar/resource_type/c_6501info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/6607reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/66072026-06-02T12:44:21Z
dc.title.none.fl_str_mv Influence of doping and controlled sn charge state on the properties and performance of SnO nanoparticles as anodes in li-ion batteries
title Influence of doping and controlled sn charge state on the properties and performance of SnO nanoparticles as anodes in li-ion batteries
spellingShingle Influence of doping and controlled sn charge state on the properties and performance of SnO nanoparticles as anodes in li-ion batteries
Vázquez López, Antonio
538.9
Doped SnO_2
Electrochemical performance
Luminescence properties
Resonant-photoemission
Hydrothermal synthesis
Optical-properties
Lithium
Composite
Fe
Ferromagnetism
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
title_short Influence of doping and controlled sn charge state on the properties and performance of SnO nanoparticles as anodes in li-ion batteries
title_full Influence of doping and controlled sn charge state on the properties and performance of SnO nanoparticles as anodes in li-ion batteries
title_fullStr Influence of doping and controlled sn charge state on the properties and performance of SnO nanoparticles as anodes in li-ion batteries
title_full_unstemmed Influence of doping and controlled sn charge state on the properties and performance of SnO nanoparticles as anodes in li-ion batteries
title_sort Influence of doping and controlled sn charge state on the properties and performance of SnO nanoparticles as anodes in li-ion batteries
dc.creator.none.fl_str_mv Vázquez López, Antonio
Maestre Varea, David
Ramírez Castellanos, Julio
González Calbet, José María
Pís, Igor
Nappini, Silvia
Yuca, Neslihan
Cremades Rodríguez, Ana Isabel
author Vázquez López, Antonio
author_facet Vázquez López, Antonio
Maestre Varea, David
Ramírez Castellanos, Julio
González Calbet, José María
Pís, Igor
Nappini, Silvia
Yuca, Neslihan
Cremades Rodríguez, Ana Isabel
author_role author
author2 Maestre Varea, David
Ramírez Castellanos, Julio
González Calbet, José María
Pís, Igor
Nappini, Silvia
Yuca, Neslihan
Cremades Rodríguez, Ana Isabel
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 538.9
Doped SnO_2
Electrochemical performance
Luminescence properties
Resonant-photoemission
Hydrothermal synthesis
Optical-properties
Lithium
Composite
Fe
Ferromagnetism
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
topic 538.9
Doped SnO_2
Electrochemical performance
Luminescence properties
Resonant-photoemission
Hydrothermal synthesis
Optical-properties
Lithium
Composite
Fe
Ferromagnetism
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
description Li-ion batteries (LiB) play nowadays a major role in several technological fields. In addition to enhanced high capacity and long cyclability, some other issues regarding safety, materials sustainability, and low cost remain unsolved. Tin oxide (SnO_2) presents several of those advantages as an anode material; however, some aspects still require to be investigated such as capacity fading over cycles. Herein, tin oxide nanoparticle-based anodes have been tested, showing high capacities and a significant cyclability over more than 150 cycles. A complementary strategy introducing doping elements such as Li and Ni during the synthesis by hydrolysis has been also evaluated versus the use of undoped materials, in order to assess the dependence on SnO_2 quality and properties of battery performance. Diverse aspects such as the Sn charge state in the synthesized nanoparticles, the variable incorporation of dopants, and the structure of defects have been considered in the understanding of the obtained capacity.
publishDate 2020
dc.date.none.fl_str_mv 2020
2020-08-27
2020
2020-08-27
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/6607
url https://hdl.handle.net/20.500.14352/6607
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869423071954206720
score 15.301603

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