Multicomponent, Functionalized HKUST-1 Analogues Assembled via Reticulation of Prefabricated Metal-Organic Polyhedral Cavities

Metal-organic frameworks (MOFs) assembled from multiple building blocks exhibit greater chemical complexity and superior functionality in practical applications. Herein, we report a new approach based on using prefabricated cavities to design isoreticular multicomponent MOFs from a known parent MOF....

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Detalles Bibliográficos
Autores: Khobotov Bakishev, Akim|||0000-0002-6119-959X, von Baeckmann, Cornelia|||0000-0002-2337-9063, Ortín-Rubio, Borja|||0000-0002-0533-3635, Hernández López, Laura|||0000-0001-6394-2538, Cortés-Martínez, Alba|||0000-0003-1679-5955, Martínez-Esaín, Jordi|||0000-0002-8420-8559, Gándara, Felipe|||0000-0002-1671-6260, Juanhuix, Judith|||0000-0003-3728-8215, Platero-Prats, Ana Eva|||0000-0002-2248-2739, Faraudo, Jordi|||0000-0002-6315-4993, Carné-Sánchez, Arnau|||0000-0002-8569-6208, Maspoch Comamala, Daniel|||0000-0003-1325-9161
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:265203
Acceso en línea:https://ddd.uab.cat/record/265203
https://dx.doi.org/urn:doi:10.1021/jacs.2c06131
Access Level:acceso abierto
Descripción
Sumario:Metal-organic frameworks (MOFs) assembled from multiple building blocks exhibit greater chemical complexity and superior functionality in practical applications. Herein, we report a new approach based on using prefabricated cavities to design isoreticular multicomponent MOFs from a known parent MOF. We demonstrate this concept with the formation of multicomponent HKUST-1 analogues, using a prefabricated cavity that comprises a cuboctahedral Rh(II) metal-organic polyhedron functionalized with 24 carboxylic acid groups. The cavities are reticulated in three dimensions via Cu(II)-paddlewheel clusters and (functionalized) 1,3,5-benzenetricarboxylate linkers to form three- and four-component HKUST-1 analogues.

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