Multicomponent, functionalized HKUST-1 analogues assembled via reticulation of prefabricated metal-organic polyhedral cavities

Metal-organic frameworks (MOFs) assembled from multiple building blocks exhibit greater chemical complexity and superior functionality in practical applications. Herein, we report a new approach based on using prefabricated cavities to design isoreticular multicomponent MOFs from a known parent MOF....

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Detalles Bibliográficos
Autores: Khobotov-Bakishev, Akim, Baeckmann, Cornelia von, Ortín-Rubio, Borja, Hernández-López, Laura, Cortés Martínez, Alba, Martínez Esaín, Jordi, Gándara Barragán, Felipe, Juanhuix, Judith, Platero Prats, Ana E., Faraudo, Jordi, Carné-Sánchez, Arnau, Maspoch, Daniel
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/283434
Acceso en línea:http://hdl.handle.net/10261/283434
https://api.elsevier.com/content/abstract/scopus_id/85136481275
Access Level:acceso abierto
Descripción
Sumario:Metal-organic frameworks (MOFs) assembled from multiple building blocks exhibit greater chemical complexity and superior functionality in practical applications. Herein, we report a new approach based on using prefabricated cavities to design isoreticular multicomponent MOFs from a known parent MOF. We demonstrate this concept with the formation of multicomponent HKUST-1 analogues, using a prefabricated cavity that comprises a cuboctahedral Rh(II) metal-organic polyhedron functionalized with 24 carboxylic acid groups. The cavities are reticulated in three dimensions via Cu(II)-paddlewheel clusters and (functionalized) 1,3,5-benzenetricarboxylate linkers to form three- and four-component HKUST-1 analogues.

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