URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling Reactions

The capacity of copper-based URJC-1-MOF as a MOF catalyst in cross-coupling reactions has been evaluated, focusing on the Chan-Lam-Evans arylation-type reactions on amines and alcohols without extra additives or ligands. The extraordinary chemical and structural stability of URJC-1-MOF and its good...

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Detalhes bibliográficos
Autores: Muñoz, Antonio, Leo, Pedro, Orcajo, Gisela, Martínez, Fernando, Calleja, Guillermo
Formato: artículo
Fecha de publicación:2019
País:España
Recursos:Universidad Rey Juan Carlos
Repositorio:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
OAI Identifier:oai:burjcdigital.urjc.es:10115/41744
Acesso em linha:https://hdl.handle.net/10115/41744
Access Level:acceso embargado
Palavra-chave:heterogeneous catalysis
URJC-1-MOF
C-N coupling
C-O coupling
Chan-Lam coupling
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spelling URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling ReactionsMuñoz, AntonioLeo, PedroOrcajo, GiselaMartínez, FernandoCalleja, Guillermoheterogeneous catalysisURJC-1-MOFC-N couplingC-O couplingChan-Lam couplingThe capacity of copper-based URJC-1-MOF as a MOF catalyst in cross-coupling reactions has been evaluated, focusing on the Chan-Lam-Evans arylation-type reactions on amines and alcohols without extra additives or ligands. The extraordinary chemical and structural stability of URJC-1-MOF and its good specific surface, make this material a promising alternative to homogeneous Cu (II) catalysts for cross-coupling reactions. URJC-1-MOF showed a remarkable catalytic activity for cross-coupling C−N and C−O reactions, higher than other heterogeneous and homogeneous copper-based catalyst, such as CuO, HKUST-1, Cu−MOF-74, Cu(OAc)2 and CuSO4⋅5H2O. Moreover, its easy recovery by simple filtration and reusability in successive runs without any loss of activity and stability, demonstrates the potential of URJC-1-MOF as an alternative catalyst for this kind of reactions in different chemical media of industrial interest.Wiley202420242019info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/10115/41744reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlosinstname:Universidad Rey Juan CarlosInglésinfo:eu-repo/semantics/embargoedAccessoai:burjcdigital.urjc.es:10115/417442026-06-24T12:48:17Z
dc.title.none.fl_str_mv URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling Reactions
title URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling Reactions
spellingShingle URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling Reactions
Muñoz, Antonio
heterogeneous catalysis
URJC-1-MOF
C-N coupling
C-O coupling
Chan-Lam coupling
title_short URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling Reactions
title_full URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling Reactions
title_fullStr URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling Reactions
title_full_unstemmed URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling Reactions
title_sort URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling Reactions
dc.creator.none.fl_str_mv Muñoz, Antonio
Leo, Pedro
Orcajo, Gisela
Martínez, Fernando
Calleja, Guillermo
author Muñoz, Antonio
author_facet Muñoz, Antonio
Leo, Pedro
Orcajo, Gisela
Martínez, Fernando
Calleja, Guillermo
author_role author
author2 Leo, Pedro
Orcajo, Gisela
Martínez, Fernando
Calleja, Guillermo
author2_role author
author
author
author
dc.subject.none.fl_str_mv heterogeneous catalysis
URJC-1-MOF
C-N coupling
C-O coupling
Chan-Lam coupling
topic heterogeneous catalysis
URJC-1-MOF
C-N coupling
C-O coupling
Chan-Lam coupling
description The capacity of copper-based URJC-1-MOF as a MOF catalyst in cross-coupling reactions has been evaluated, focusing on the Chan-Lam-Evans arylation-type reactions on amines and alcohols without extra additives or ligands. The extraordinary chemical and structural stability of URJC-1-MOF and its good specific surface, make this material a promising alternative to homogeneous Cu (II) catalysts for cross-coupling reactions. URJC-1-MOF showed a remarkable catalytic activity for cross-coupling C−N and C−O reactions, higher than other heterogeneous and homogeneous copper-based catalyst, such as CuO, HKUST-1, Cu−MOF-74, Cu(OAc)2 and CuSO4⋅5H2O. Moreover, its easy recovery by simple filtration and reusability in successive runs without any loss of activity and stability, demonstrates the potential of URJC-1-MOF as an alternative catalyst for this kind of reactions in different chemical media of industrial interest.
publishDate 2019
dc.date.none.fl_str_mv 2019
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10115/41744
url https://hdl.handle.net/10115/41744
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv info:eu-repo/semantics/embargoedAccess
eu_rights_str_mv embargoedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
instname:Universidad Rey Juan Carlos
instname_str Universidad Rey Juan Carlos
reponame_str BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
collection BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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