Metal-Catalyzed Reductive Coupling Reactions of Organic Halides with Carbonyl-Type Compounds

<p> Metal-catalyzed reductive coupling reactions of aryl halides and (pseudo)halides with carbonyl-type compounds have undergone an impressive development within the last years. These methodologies have shown to be a powerful alternate strategy, practicality aside, to the use of stoichiometric...

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Bibliographic Details
Authors: Moragas, Antoni, Correa, Arkaitz, Martin, Ruben
Format: article
Publication Date:2014
Country:España
Institution:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repository:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305829
Online Access:http://hdl.handle.net/2072/305829
https://doi.org/10.1002/chem.201402509
Access Level:Open access
Keyword:carbonyl compounds
C-C coupling
halides
reductive couplings
Description
Summary:<p> Metal-catalyzed reductive coupling reactions of aryl halides and (pseudo)halides with carbonyl-type compounds have undergone an impressive development within the last years. These methodologies have shown to be a powerful alternate strategy, practicality aside, to the use of stoichiometric, well-defined, and, in some cases, air-sensitive organometallic species. In this Minireview, the recent findings in this field are summarized, with particular emphasis on the mechanistic interpretation of the results and future aspects of this area of expertise.</p>