Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones

Solvothermally promoted assembly of the multifunctional 3-amino-4-hydroxybenzoic acid ligand with the corresponding Eu salt gives rise to the formation of a porous metal-organic framework with the general formula {[EuL(OH)(HO)] ⋅ 5DMF} (1) that has been tested as heterogeneous catalyst for the cyano...

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Autores: Pérez, Juana M., Echenique-Errandonea, Estitxu, Rojas, Sara, Choquesillo-Lazarte, Duane, Seco, José M., López-Vargas, Mireya E., Rodríguez-Diéguez, Antonio, Fernández, Ignacio
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/356885
Acceso en línea:http://hdl.handle.net/10261/356885
Access Level:acceso abierto
Palabra clave:Cyanosilylation
Europium
Heterogeneous catalysis
Ketones
Metal-organic framework
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spelling Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding KetonesPérez, Juana M.Echenique-Errandonea, EstitxuRojas, SaraChoquesillo-Lazarte, DuaneSeco, José M.López-Vargas, Mireya E.Rodríguez-Diéguez, AntonioFernández, IgnacioCyanosilylationEuropiumHeterogeneous catalysisKetonesMetal-organic frameworkSolvothermally promoted assembly of the multifunctional 3-amino-4-hydroxybenzoic acid ligand with the corresponding Eu salt gives rise to the formation of a porous metal-organic framework with the general formula {[EuL(OH)(HO)] ⋅ 5DMF} (1) that has been tested as heterogeneous catalyst for the cyanosilylation of a broad scope of ketones in solvent-free conditions, using the lowest catalyst loading of 0.5 mol% ever reported, and exhibiting no leak and high recyclability.This research has been funded by the State Research Agency (grants CTQ2017‐84334‐R and PGC2018‐102052‐B−C21) of the Spanish Ministry of Science, Innovation and Universities, the European Union (European Regional Development Fund – ERDF), Junta de Andalucía (102 C2000004, CV20‐78799, P20_01041, UAL‐FEDER UAL2020‐AGR−B1781, FQM‐376 and FQM‐394) and Gobierno de España MCIN/AEI/10.13039/501100011033/Unión Europea “Next GenerationEU”/PRTR (programs PDC2021‐121248‐I00 and PLEC2021‐007774). E.E. is grateful to the Government of the Basque Country for the predoctoral fellowship, S.R. acknowledges the Juan de la Cierva Incorporación Fellowship (grant agreement no. IJC2019‐038894‐I) and JMP an Hipatia fellowship (University of Almería, grant no. HIPATIA2021 04).Wiley-VCHAgencia Estatal de Investigación (España)Ministerio de Ciencia e Innovación (España)Ministerio de Ciencia, Innovación y Universidades (España)Junta de AndalucíaUniversidad de AlmeríaConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2024202420222024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/356885reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#nfo:eu-repo/grantAgreement/MCIN//PGC2018‐102052‐B−C21nfo:eu-repo/grantAgreement/MCIN//CTQ2017‐84334‐Rinfo:eu-repo/grantAgreement/MCIN/AEI/10.13039http://dx.doi.org/10.1002/cctc.202200967Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3568852026-05-22T06:33:51Z
dc.title.none.fl_str_mv Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones
title Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones
spellingShingle Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones
Pérez, Juana M.
Cyanosilylation
Europium
Heterogeneous catalysis
Ketones
Metal-organic framework
title_short Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones
title_full Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones
title_fullStr Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones
title_full_unstemmed Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones
title_sort Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones
dc.creator.none.fl_str_mv Pérez, Juana M.
Echenique-Errandonea, Estitxu
Rojas, Sara
Choquesillo-Lazarte, Duane
Seco, José M.
López-Vargas, Mireya E.
Rodríguez-Diéguez, Antonio
Fernández, Ignacio
author Pérez, Juana M.
author_facet Pérez, Juana M.
Echenique-Errandonea, Estitxu
Rojas, Sara
Choquesillo-Lazarte, Duane
Seco, José M.
López-Vargas, Mireya E.
Rodríguez-Diéguez, Antonio
Fernández, Ignacio
author_role author
author2 Echenique-Errandonea, Estitxu
Rojas, Sara
Choquesillo-Lazarte, Duane
Seco, José M.
López-Vargas, Mireya E.
Rodríguez-Diéguez, Antonio
Fernández, Ignacio
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Agencia Estatal de Investigación (España)
Ministerio de Ciencia e Innovación (España)
Ministerio de Ciencia, Innovación y Universidades (España)
Junta de Andalucía
Universidad de Almería
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Cyanosilylation
Europium
Heterogeneous catalysis
Ketones
Metal-organic framework
topic Cyanosilylation
Europium
Heterogeneous catalysis
Ketones
Metal-organic framework
description Solvothermally promoted assembly of the multifunctional 3-amino-4-hydroxybenzoic acid ligand with the corresponding Eu salt gives rise to the formation of a porous metal-organic framework with the general formula {[EuL(OH)(HO)] ⋅ 5DMF} (1) that has been tested as heterogeneous catalyst for the cyanosilylation of a broad scope of ketones in solvent-free conditions, using the lowest catalyst loading of 0.5 mol% ever reported, and exhibiting no leak and high recyclability.
publishDate 2022
dc.date.none.fl_str_mv 2022
2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/356885
url http://hdl.handle.net/10261/356885
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
nfo:eu-repo/grantAgreement/MCIN//PGC2018‐102052‐B−C21
nfo:eu-repo/grantAgreement/MCIN//CTQ2017‐84334‐R
info:eu-repo/grantAgreement/MCIN/AEI/10.13039
http://dx.doi.org/10.1002/cctc.202200967
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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