Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones
Solvothermally promoted assembly of the multifunctional 3-amino-4-hydroxybenzoic acid ligand with the corresponding Eu salt gives rise to the formation of a porous metal-organic framework with the general formula {[EuL(OH)(HO)] ⋅ 5DMF} (1) that has been tested as heterogeneous catalyst for the cyano...
| Autores: | , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/356885 |
| Acceso en línea: | http://hdl.handle.net/10261/356885 |
| Access Level: | acceso abierto |
| Palabra clave: | Cyanosilylation Europium Heterogeneous catalysis Ketones Metal-organic framework |
| Sumario: | Solvothermally promoted assembly of the multifunctional 3-amino-4-hydroxybenzoic acid ligand with the corresponding Eu salt gives rise to the formation of a porous metal-organic framework with the general formula {[EuL(OH)(HO)] ⋅ 5DMF} (1) that has been tested as heterogeneous catalyst for the cyanosilylation of a broad scope of ketones in solvent-free conditions, using the lowest catalyst loading of 0.5 mol% ever reported, and exhibiting no leak and high recyclability. |
|---|