Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review

[EN] Hybrid organic-inorganic catalysts have been extensively investigated by several research groups in the last decades, as they allow combining the structural robust-ness of inorganic solids with the versatility of organic chemistry. Within the field of hybrid catalysts, synthetic strategies base...

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Autores: Erigoni, Andrea, Díaz, Urbano|||0000-0003-1472-8724
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/182968
Acceso en línea:https://riunet.upv.es/handle/10251/182968
Access Level:acceso abierto
Palabra clave:Organic-inorganic hybrid composites
Porous-materials
Catalysis
Silica-based materials
Sol-gel synthesis
Post-synthetic functionalization
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spelling Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A ReviewErigoni, AndreaDíaz, Urbano|||0000-0003-1472-8724Organic-inorganic hybrid compositesPorous-materialsCatalysisSilica-based materialsSol-gel synthesisPost-synthetic functionalization[EN] Hybrid organic-inorganic catalysts have been extensively investigated by several research groups in the last decades, as they allow combining the structural robust-ness of inorganic solids with the versatility of organic chemistry. Within the field of hybrid catalysts, synthetic strategies based on silica are among the most exploitable, due to the convenience of sol-gel chemistry, to the array of silyl-derivative precursors that can be synthesized and to the number of post-synthetic functionalization strategies available, amongst others. This review proposes to highlight these advantages, firstly describing the most common synthetic tools and the chemistry behind sol-gel syntheses of hybrid catalysts, then presenting exemplificative studies involving mono- and multi-functional silica-based hybrid catalysts featuring different types of active sites (acid, base, redox). Materials obtained through different approaches are described and their properties, as well as their catalytic performances, are compared. The general scope of this review is to gather useful information for those approaching the synthesis of organic-inorganic hybrid materials, while providing an overview on the state-of-the art in the synthesis of such materials and highlighting their capacities.This research was funded by Spanish Government (MAT2017-82288-C2-1-P and Severo Ochoa Excellence Program SEV-2016-0683) and MULTY2HYCAT (EU-Horizon 2020 funded project under grant agreement no. 720783).MDPI AGInstituto Universitario Mixto de Tecnología QuímicaEuropean CommissionAgencia Estatal de InvestigaciónMinisterio de Economía, Industria y CompetitividadRepositorio Institucional de la Universitat Politècnica de València Riunet20212021-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/182968reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016 MAT2017-82288-C2-1-P MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVASMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 SEV-2016-0683European Commission https://doi.org/10.13039/501100000780 H2020 720783open accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento (by)http://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1829682026-06-13T07:49:27Z
dc.title.none.fl_str_mv Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review
title Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review
spellingShingle Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review
Erigoni, Andrea
Organic-inorganic hybrid composites
Porous-materials
Catalysis
Silica-based materials
Sol-gel synthesis
Post-synthetic functionalization
title_short Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review
title_full Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review
title_fullStr Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review
title_full_unstemmed Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review
title_sort Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review
dc.creator.none.fl_str_mv Erigoni, Andrea
Díaz, Urbano|||0000-0003-1472-8724
author Erigoni, Andrea
author_facet Erigoni, Andrea
Díaz, Urbano|||0000-0003-1472-8724
author_role author
author2 Díaz, Urbano|||0000-0003-1472-8724
author2_role author
dc.contributor.none.fl_str_mv Instituto Universitario Mixto de Tecnología Química
European Commission
Agencia Estatal de Investigación
Ministerio de Economía, Industria y Competitividad
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Organic-inorganic hybrid composites
Porous-materials
Catalysis
Silica-based materials
Sol-gel synthesis
Post-synthetic functionalization
topic Organic-inorganic hybrid composites
Porous-materials
Catalysis
Silica-based materials
Sol-gel synthesis
Post-synthetic functionalization
description [EN] Hybrid organic-inorganic catalysts have been extensively investigated by several research groups in the last decades, as they allow combining the structural robust-ness of inorganic solids with the versatility of organic chemistry. Within the field of hybrid catalysts, synthetic strategies based on silica are among the most exploitable, due to the convenience of sol-gel chemistry, to the array of silyl-derivative precursors that can be synthesized and to the number of post-synthetic functionalization strategies available, amongst others. This review proposes to highlight these advantages, firstly describing the most common synthetic tools and the chemistry behind sol-gel syntheses of hybrid catalysts, then presenting exemplificative studies involving mono- and multi-functional silica-based hybrid catalysts featuring different types of active sites (acid, base, redox). Materials obtained through different approaches are described and their properties, as well as their catalytic performances, are compared. The general scope of this review is to gather useful information for those approaching the synthesis of organic-inorganic hybrid materials, while providing an overview on the state-of-the art in the synthesis of such materials and highlighting their capacities.
publishDate 2021
dc.date.none.fl_str_mv 2021
2021-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/182968
url https://riunet.upv.es/handle/10251/182968
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016 MAT2017-82288-C2-1-P MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 SEV-2016-0683
European Commission https://doi.org/10.13039/501100000780 H2020 720783
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv MDPI AG
publisher.none.fl_str_mv MDPI AG
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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