Photoreactivity and Novel Designs in Smart Chiral Materials
Helical polymers, covalent and supramolecular, have attracted the attention of the scientific community for the relation structure/function found in helical biomacromolecules such as peptides, proteins, DNA. Inspired by these works, in this thesis photochemical properties of several synthetic helica...
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| Tipo de recurso: | tesis doctoral |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Universidad de Santiago de Compostela (USC) |
| Repositorio: | Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela |
| Idioma: | inglés |
| OAI Identifier: | oai:minerva.usc.gal:10347/29950 |
| Acceso en línea: | http://hdl.handle.net/10347/29950 |
| Access Level: | acceso abierto |
| Palabra clave: | Materias::Investigación::23 Química::2304 Química macromolecular::230408 Macromoléculas Materias::Investigación::23 Química::2304 Química macromolecular::230422 Estabilidad de las macromoléculas Materias::Investigación::23 Química::2304 Química macromolecular::230410 Química de los monómeros |
| Sumario: | Helical polymers, covalent and supramolecular, have attracted the attention of the scientific community for the relation structure/function found in helical biomacromolecules such as peptides, proteins, DNA. Inspired by these works, in this thesis photochemical properties of several synthetic helical polymers from poly(phenylacetylene)s were studied, and the results were applied to elucidate its secondary structure. Furthermore, new helical systems, covalent and supramolecular were prepared and studied, resulting in novel multi-responsive and multi-helical materials. |
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