Pectin-cellulose nanocrystal biocomposites: Tuning of physical properties and biodegradability

The fabrication of pectin-cellulose nanocrystal (CNC) biocomposites has been systematically investigated by blending both polysaccharides at different relative concentrations. Circular free-standing films with a diameter of 9 cm were prepared by simple solution of these carbohydrates in water follow...

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Detalhes bibliográficos
Autores: González Moreno, Ana, Guzmán-Puyol, Susana, Domínguez, Eva, Benítez, José J., Segado, Patricia, Lauciello, Simone, Ceseracciu, Luca, Porras-Vázquez, José M, Leon-Reina, Laura, Heredia, Antonio, Heredia-Guerrero, José A.
Tipo de documento: artigo
Estado:Versión aceptada para publicación
Data de publicação:2021
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositório:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/374426
Acesso em linha:http://hdl.handle.net/10261/374426
https://api.elsevier.com/content/abstract/scopus_id/85103125937
Access Level:Acceso aberto
Palavra-chave:Biocomposites
Biodegradability
Cellulose nanocrystal
Film formation
Pectin
Descrição
Resumo:The fabrication of pectin-cellulose nanocrystal (CNC) biocomposites has been systematically investigated by blending both polysaccharides at different relative concentrations. Circular free-standing films with a diameter of 9 cm were prepared by simple solution of these carbohydrates in water followed by drop-casting and solvent evaporation. The addition of pectin allows to finely tune the properties of the biocomposites. Textural characterization by AFM showed fibrous morphology and an increase in fiber diameter with pectin content. XRD analysis demonstrated that pectin incorporation also reduced the degree of crystallinity though no specific interaction between both polysaccharides was detected, by ATR-FTIR spectroscopy. The optical properties of these biocomposites were characterized for the first time and it was found that pectin in the blend reduced the reflectance of visible light and increased UV absorbance. Thermal stability, analyzed by TGA, was improved with the incorporation of pectin. Finally, pec