Optimized and scaled-up production of cellulose-reinforced biodegradable composite films made up of carrot processing waste

The ever-growing environmental concern arising from the unrestricted exploitation of fossil sources for the massive production of non-biodegradable materials encourages research on alternative renewable resources. We herein pave the route for the production of biodegradable biocomposites made up of...

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Detalles Bibliográficos
Autores: Otoni, Caio G., Lodi, Beatriz D., Lorevice, Marcos V., Leitao, Renato C., Ferreira, Marcos D., Moura, Marcia R. de [UNESP], Mattoso, Luiz H. C.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2018
País:Brasil
Institución:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/164405
Acceso en línea:http://dx.doi.org/10.1016/j.indcrop.2018.05.003
http://hdl.handle.net/11449/164405
Access Level:acceso abierto
Palabra clave:Biopolymer
Cellulose derivative
Biocomposite
Daucus carota L.
Residue
Biodegradability
Descripción
Sumario:The ever-growing environmental concern arising from the unrestricted exploitation of fossil sources for the massive production of non-biodegradable materials encourages research on alternative renewable resources. We herein pave the route for the production of biodegradable biocomposites made up of carrot minimal processing waste (CMPW) by optimizing its combination with hydroxypropyl methylcellulose (HPMC) and high-pressure microfluidized cellulose fibers, which played ligand and mechanical reinforcement roles, respectively. Ternary mixture designs established mathematical models aimed at structure-composition-property correlations, allowing their mechanical performances to be innovatively predicted without the need for further experiments. The optimized formulation comprised 33 wt.% CPMW and led to biodegradable biocomposites featuring ca. 30 MPa of tensile strength, ca. 3% elongation at break, and ca. 2 GPa of Young's modulus, properties which are suitable for food packaging applications. Finally, the film-forming protocol was successfully scaled-up through a continuous casting approach, allowing the production of 1.56 m(2) of biodegradable biocomposite in each hour. While scaling up did not affect film's barrier to moisture, it did impair its mechanical behavior.