Identification of Degradation Mechanisms in Slot-Die-Coated Nonfullerene ITO-Free Organic Solar Cells Using Different Illumination Spectra

This work has been supported by Comunidad de Madrid under the SINFOTON2-CM Research Program (S2018/NMT-4326-SINFOTON2-CM) and the Spanish Ministry of Economy, the Agencia Estatal de Investigación and European Union’s FEDER under the TEC2016-77242-C1/C2/C3 AEI/FEDER, UE Projects. The work of E. López...

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Autores: Arredondo, Belén, del Pozo, Gonzalo, Hernández-Balaguera, Enrique, Martin-Martin, Diego, López-Gonzalez, Maria del Carmen, Romero, Beatriz, Lopez-Fraguas, Eduardo, Vergaz, Rcardo, Quintana, Xabier, Lamminaho, Jani, Destouesse, Elodie, Ahmadpour, Mehrdad, Turkovic, Vida, Madsen, Morten
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universidad Rey Juan Carlos
Repositorio:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
OAI Identifier:oai:burjcdigital.urjc.es:10115/28256
Acceso en línea:https://hdl.handle.net/10115/28256
Access Level:acceso embargado
Palabra clave:Organic solar cells
degradation
non-fullerene
slot-die coating
ITO-free
flexible
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spelling Identification of Degradation Mechanisms in Slot-Die-Coated Nonfullerene ITO-Free Organic Solar Cells Using Different Illumination SpectraArredondo, Beléndel Pozo, GonzaloHernández-Balaguera, EnriqueMartin-Martin, DiegoLópez-Gonzalez, Maria del CarmenRomero, BeatrizLopez-Fraguas, EduardoVergaz, RcardoQuintana, XabierLamminaho, JaniDestouesse, ElodieAhmadpour, MehrdadTurkovic, VidaMadsen, MortenOrganic solar cellsdegradationnon-fullereneslot-die coatingITO-freeflexibleThis work has been supported by Comunidad de Madrid under the SINFOTON2-CM Research Program (S2018/NMT-4326-SINFOTON2-CM) and the Spanish Ministry of Economy, the Agencia Estatal de Investigación and European Union’s FEDER under the TEC2016-77242-C1/C2/C3 AEI/FEDER, UE Projects. The work of E. López- Fraguas was supported by the Ministerio de Educación y Formación Profesional for his Doctoral Grant through FPU Research Fellowship under Grant FPU17/00612. M.M., J.L, E.D. and V.T. acknowledge that part of this work has been developed within the RollFlex project, part-financed by Interreg Deutschland-Danmark with means from the European Regional Development Fund and the Southern Denmark Growth Forum. M.M. and V.T. acknowledge the support from the Villum Foundation for Project CompliantPV (Grant No. 13365). Finally, all authors acknowledge the support from EU Framework Programme Horizon 2020 for MNPS COST ACTION MP1307 StableNextSol.In this work, we have studied degradation mechanisms of nonfullerene-based organic solar cells with PET/Ag/ZnO/ PBDTB-T:ITIC/PEDOT:PSS/CPP PEDOT:PSS device structure. We compare pristine and degraded samples that were subjected to outdoor degradation following the standard ISOS-O2 protocol. The ideality factors for different incident wavelengths obtained from open-circuit voltage vs irradiation level and current density-voltage (J-V) measurements at different temperatures indicate that for aged samples recombination is governed by the Shockley-Read-Hall mechanism occurring in a region near the anode. Samples were also characterized using impedance spectroscopy (IS) and fitted to an electrical model. Impedance parameters were used to obtain mobility, indicating a clear degradation of the active layer blend for aged samples. The change in the chemical capacitance also reveals a worsening in carrier extraction. Finally, two-dimensional (2D) numerical simulations and fits to experimental J-V curves confirm the existence of a layer near the anode contact with poorer mobility and a decrease in the anode work function (WF) for the degraded samples.ACS202420242020info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/10115/28256reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlosinstname:Universidad Rey Juan CarlosInglésinfo:eu-repo/semantics/embargoedAccessoai:burjcdigital.urjc.es:10115/282562026-06-24T12:48:17Z
dc.title.none.fl_str_mv Identification of Degradation Mechanisms in Slot-Die-Coated Nonfullerene ITO-Free Organic Solar Cells Using Different Illumination Spectra
title Identification of Degradation Mechanisms in Slot-Die-Coated Nonfullerene ITO-Free Organic Solar Cells Using Different Illumination Spectra
spellingShingle Identification of Degradation Mechanisms in Slot-Die-Coated Nonfullerene ITO-Free Organic Solar Cells Using Different Illumination Spectra
Arredondo, Belén
Organic solar cells
degradation
non-fullerene
slot-die coating
ITO-free
flexible
title_short Identification of Degradation Mechanisms in Slot-Die-Coated Nonfullerene ITO-Free Organic Solar Cells Using Different Illumination Spectra
title_full Identification of Degradation Mechanisms in Slot-Die-Coated Nonfullerene ITO-Free Organic Solar Cells Using Different Illumination Spectra
title_fullStr Identification of Degradation Mechanisms in Slot-Die-Coated Nonfullerene ITO-Free Organic Solar Cells Using Different Illumination Spectra
title_full_unstemmed Identification of Degradation Mechanisms in Slot-Die-Coated Nonfullerene ITO-Free Organic Solar Cells Using Different Illumination Spectra
title_sort Identification of Degradation Mechanisms in Slot-Die-Coated Nonfullerene ITO-Free Organic Solar Cells Using Different Illumination Spectra
dc.creator.none.fl_str_mv Arredondo, Belén
del Pozo, Gonzalo
Hernández-Balaguera, Enrique
Martin-Martin, Diego
López-Gonzalez, Maria del Carmen
Romero, Beatriz
Lopez-Fraguas, Eduardo
Vergaz, Rcardo
Quintana, Xabier
Lamminaho, Jani
Destouesse, Elodie
Ahmadpour, Mehrdad
Turkovic, Vida
Madsen, Morten
author Arredondo, Belén
author_facet Arredondo, Belén
del Pozo, Gonzalo
Hernández-Balaguera, Enrique
Martin-Martin, Diego
López-Gonzalez, Maria del Carmen
Romero, Beatriz
Lopez-Fraguas, Eduardo
Vergaz, Rcardo
Quintana, Xabier
Lamminaho, Jani
Destouesse, Elodie
Ahmadpour, Mehrdad
Turkovic, Vida
Madsen, Morten
author_role author
author2 del Pozo, Gonzalo
Hernández-Balaguera, Enrique
Martin-Martin, Diego
López-Gonzalez, Maria del Carmen
Romero, Beatriz
Lopez-Fraguas, Eduardo
Vergaz, Rcardo
Quintana, Xabier
Lamminaho, Jani
Destouesse, Elodie
Ahmadpour, Mehrdad
Turkovic, Vida
Madsen, Morten
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Organic solar cells
degradation
non-fullerene
slot-die coating
ITO-free
flexible
topic Organic solar cells
degradation
non-fullerene
slot-die coating
ITO-free
flexible
description This work has been supported by Comunidad de Madrid under the SINFOTON2-CM Research Program (S2018/NMT-4326-SINFOTON2-CM) and the Spanish Ministry of Economy, the Agencia Estatal de Investigación and European Union’s FEDER under the TEC2016-77242-C1/C2/C3 AEI/FEDER, UE Projects. The work of E. López- Fraguas was supported by the Ministerio de Educación y Formación Profesional for his Doctoral Grant through FPU Research Fellowship under Grant FPU17/00612. M.M., J.L, E.D. and V.T. acknowledge that part of this work has been developed within the RollFlex project, part-financed by Interreg Deutschland-Danmark with means from the European Regional Development Fund and the Southern Denmark Growth Forum. M.M. and V.T. acknowledge the support from the Villum Foundation for Project CompliantPV (Grant No. 13365). Finally, all authors acknowledge the support from EU Framework Programme Horizon 2020 for MNPS COST ACTION MP1307 StableNextSol.
publishDate 2020
dc.date.none.fl_str_mv 2020
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10115/28256
url https://hdl.handle.net/10115/28256
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv info:eu-repo/semantics/embargoedAccess
eu_rights_str_mv embargoedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv ACS
publisher.none.fl_str_mv ACS
dc.source.none.fl_str_mv reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
instname:Universidad Rey Juan Carlos
instname_str Universidad Rey Juan Carlos
reponame_str BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
collection BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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